Journal
PURE AND APPLIED CHEMISTRY
Volume 80, Issue 5, Pages 1005-1012Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200880051005
Keywords
active metals; nickel; copper; iron; nanoparticles; reduction; alkylation of ketones with alcohols
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Active transition metals, namely, nickel, copper and iron, have been prepared by the reduction of the corresponding chlorides with lithium and a catalytic amount of an arene. These metals, in the form of nanoparticles, have found application in the reduction of a wide variety of functional groups as well as in the alkylation of methyl ketones with primary alcohols.
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