Journal
ACS CATALYSIS
Volume 5, Issue 6, Pages 3609-3612Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b00583
Keywords
phase transfer catalysis; hydroxylation; alpha-hydroxy ketone; oxygen; cinchona alkaloid; enantioselectivity
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Funding
- Singapore National Research Foundation (NRF Fellowship)
- National University of Singapore
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An efficient and enantioselective alpha-hydroxylation of acyclic as well as cyclic ketones using molecular oxygen has been developed. This simple catalytic procedure uses a readily available phase transfer catalyst and produces a wide range of valuable tertiary a-hydroxy ketones in good to excellent enantiopurity.
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