Journal
ACS CATALYSIS
Volume 5, Issue 11, Pages 7008-7014Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b01992
Keywords
hypervalent iodine; diaryliodonium salts; copper; amination; regioselectivity
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Funding
- Latvian Science Council [274/2012]
- European Social Fund within the project Support for Doctoral Studies at University of Latvia
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A one-pot two-step method for para-selective C-H amination of carbocyclic arenes comprises the in situ formation of unsymmetrical diaryl-lambda(3)-iodanes followed by their Cu(I)-catalyzed reaction with a range of N-unprotected amines.
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