4.7 Article

Characterization of tandem organic solar cells comprising subcells of identical absorber material

Journal

PROGRESS IN PHOTOVOLTAICS
Volume 23, Issue 10, Pages 1353-1356

Publisher

WILEY-BLACKWELL
DOI: 10.1002/pip.2541

Keywords

tandem organic solar cell; characterization; spectral response; external quantum efficiency

Ask authors/readers for more resources

Recently organic tandem solar cells with record efficiency had been shown comprising identical absorber materials in both subcells. Such structures pose new challenges for characterization. The standard test methods for measuring spectral response of tandem solar cells can not be applied. The standard procedures demand for different bias illumination during measuring spectral response allowing to select the subcell being current limiting. With subcells comprising identical absorber materials, thus having identical absorption spectra, such a selection is not trivial. In this paper, we show that with the help of detailed optical simulations of such tandem organic solar cells, their characterization is possible, and we apply the proposed method to a sample structure. Copyright (C) 2014 John Wiley & Sons, Ltd.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Physical

In Situ Observations of the Growth Mode of Vacuum-Deposited α-Sexithiophene

T. L. Derrien, A. E. Lauritzen, P. Kaienburg, J. F. M. Hardigree, C. Nicklin, M. Riede

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

Article Chemistry, Physical

Ultrafast Charge Dynamics in Dilute-Donor versus Highly Intermixed TAPC:C60 Organic Solar Cell Blends

Gareth John Moore, Martina Causa', Josue F. Martinez Hardigree, Safakath Karuthedath, Ivan Ramirez, Anna Jungbluth, Frederic Laquai, Moritz Riede, Natalie Banerji

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2020)

Article Chemistry, Multidisciplinary

Molecular Quadrupole Moments Promote Ground-State Charge Generation in Doped Organic Semiconductors

Alberto Privitera, Giacomo Londi, Moritz Riede, Gabriele D'Avino, David Beljonne

ADVANCED FUNCTIONAL MATERIALS (2020)

Article Nanoscience & Nanotechnology

Chain Conformation Control of Fluorene-Benzothiadiazole Copolymer Light-Emitting Diode Efficiency and Lifetime

Bingjun Wang, Hao Ye, Moritz Riede, Donal D. C. Bradley

Summary: The introduction of beta-phase chain segments into the copolymer 90F8:10BT significantly improves the performance of LEDs, confirming the effectiveness of chain conformation control for fluorene-based homo- and copolymer device optimization.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Multidisciplinary Sciences

The role of spin in the degradation of organic photovoltaics

Ivan Ramirez, Alberto Privitera, Safakath Karuthedath, Anna Jungbluth, Johannes Benduhn, Andreas Sperlich, Donato Spoltore, Koen Vandewal, Frederic Laquai, Moritz Riede

Summary: Stability is crucial for the commercialization of organic photovoltaic (OPV) devices. Triplet states, particularly through back-hole transfer (BHT), play a significant role in the photo-degradation of fullerene-based devices. The impact of electron and hole back transfer on BHJ stability should be carefully considered in the design of stable OPV devices.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Organic Solar Cells-The Path to Commercial Success

Moritz Riede, Donato Spoltore, Karl Leo

Summary: Organic solar cells have the potential to be the cheapest form of electricity, surpassing silicon photovoltaics. However, challenges remain in increasing efficiency and long-term stability. The technology could be used in building integrated photovoltaics and portable electronics, with the potential to have the lowest carbon footprint of all energy generation technologies.

ADVANCED ENERGY MATERIALS (2021)

Article Materials Science, Multidisciplinary

Direct observation and evolution of electronic coupling between organic semiconductors

Sameer Vajjala Kesava, Moritz K. Riede

Summary: The electronic wave functions of atoms or molecules are influenced by their interactions with the environment. The in situ spectroscopic ellipsometry data analysis method called DART allows for direct observation of electronic coupling along the thickness direction. This method is applicable for studying electronic coupling between vapor-deposited materials systems where real-time measurements during thin film growth are possible.

PHYSICAL REVIEW MATERIALS (2021)

Article Materials Science, Multidisciplinary

Perspectives of Organic and Perovskite-Based Spintronics

Alberto Privitera, Marcello Righetto, Franco Cacialli, Moritz K. Riede

Summary: Spin-related phenomena in optoelectronic materials have promising applications in various technological areas, with organic semiconductors and halide perovskites playing a key role in driving forward this field. The development of organic- and perovskite-based spintronics enables control over spin, charges, and photons in devices, with potential applications in new multifunctional spintronic devices.

ADVANCED OPTICAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

Assessing the Photovoltaic Quality of Vacuum-Thermal Evaporated Organic Semiconductor Blends

Pascal Kaienburg, Anna Jungbluth, Irfan Habib, Sameer Vajjala Kesava, Mathias Nyman, Moritz K. Riede

Summary: Vacuum-thermal evaporation (VTE) is an important fabrication route for organic solar cells (OSCs) and can reach high extinction coefficients, but only moderate carrier mobility and voltage loss compared to solution-processed counterparts. Improvement is needed for VTE OSCs to catch up in terms of power conversion efficiency.

ADVANCED MATERIALS (2022)

Article Nanoscience & Nanotechnology

Properties and Applications of Copper(I) Thiocyanate Hole-Transport Interlayers Processed from Different Solvents

Bingjun Wang, Sungho Nam, Saurav Limbu, Ji-Seon Kim, Moritz Riede, Donal D. C. Bradley

Summary: This paper reports on the use of N,N-dimethylformamide (DMF) and 1-methyl-2-pyrrolidinone (NMP) as alternative solvents for copper(I) thiocyanate (CuSCN) interlayers. The properties of CuSCN layers processed from DMF and NMP are compared to those processed from traditional solvents and other recent alternatives. The study discusses the surface roughness, polymorphism, and surface chemistry of the resulting CuSCN layers, as well as the interlayer surface energy and ionization potential. The overall suitability of dimethyl sulfoxide (DMSO) and DMF as solvents for CuSCN interlayer deposition is demonstrated through device tests.

ADVANCED ELECTRONIC MATERIALS (2022)

Article Nanoscience & Nanotechnology

Vacuum-Deposited Donors for Low-Voltage-Loss Nonfullerene Organic Solar Cells

Pascal Kaienburg, Helen Bristow, Anna Jungbluth, Irfan Habib, Iain McCulloch, David Beljonne, Moritz Riede

Summary: The advent of nonfullerene acceptors (NFAs) has achieved over 19% power conversion efficiency in laboratory organic photovoltaics (OPVs). However, high-efficiency NFAs have only been realized in solution-processed blends. Vacuum thermal evaporation (VTE) is crucial for real-world OPV commercialization due to its successful track record in upscaled industrial production. In this study, we demonstrate that using VTE donors with NFAs instead of the current standard acceptor C-60 can significantly reduce voltage losses, highlighting the immense potential of evaporable NFAs and the urgent need for smaller, evaporable compounds.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Nanoscience & Nanotechnology

Vacuum deposited organic solar cells with BTIC-H as A-D-A non-fullerene acceptor

Irfan Habib, Pascal Kaienburg, Dondong Xia, Olivia Gough, Ming Zhu, Joseph Spruce, Weiwei Li, Moritz Riede

Summary: Since non-fullerene acceptors (NFAs) replaced fullerene derivatives, the power conversion efficiency of solution-processed organic solar cells (OSCs) has almost doubled. However, the successful transition from C-60 to NFAs is still pending for vacuum-thermal evaporated (VTE) OSCs due to the size limitation of NFAs. Discovering high-performing VTE NFAs is crucial for industrial manufacturing.

APL MATERIALS (2023)

Article Materials Science, Multidisciplinary

Charge transfer state characterization and voltage losses of organic solar cells

Anna Jungbluth, Pascal Kaienburg, Moritz Riede

Summary: A correct determination of voltage losses is crucial for improving the performance of organic solar cells. This paper summarizes different methods for calculating voltage losses and provides a detailed discussion on important models for characterizing charge transfer state properties.

JOURNAL OF PHYSICS-MATERIALS (2022)

Article Chemistry, Physical

A liquid-crystalline non-fullerene acceptor enabling high-performance organic solar cells

Pierluigi Mondelli, Francesco Silvestri, Laura Ciammaruchi, Eduardo Solano, Eduardo Beltran-Gracia, Esther Barrena, Moritz Riede, Graham Morse

Summary: The study introduces a Non-Fullerene Acceptor (NFA) 4TICO with improved structural flexibility, leading to enhanced performance of organic photovoltaics by optimizing bulk heterojunction morphology and reducing structural defects. In-depth investigation of the NFA's structural properties in relation to solar cell performance and charge transport is conducted, demonstrating improved short-circuit current and fill factor.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Materials Science, Multidisciplinary

Efficiency enhancement of small molecule organic solar cells using hexapropyltruxene as an interface layer

Hanyang Ye, Sameer Vajjala Kesava, Josue F. Martinez Hardigree, Roisin E. Brown, Giulio Mazzotta, Ross Warren, Peter J. Skabara, Moritz Riede

JOURNAL OF MATERIALS CHEMISTRY C (2020)

No Data Available