Journal
PROGRESS IN PHOTOVOLTAICS
Volume 23, Issue 5, Pages 660-670Publisher
WILEY
DOI: 10.1002/pip.2478
Keywords
PERT; PERL; metallization; nickel silicide; Cu plating
Funding
- (IIAP) photovoltaic program
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In this paper, we evaluate p-type passivated emitter and rear locally diffused (p-PERL) and n-type passivated emitter and rear totally diffused (n-PERT) large area silicon solar cells featuring nickel/copper/silver (Ni/Cu/Ag) plated front side contacts. By using front emitter p-PERL and rear emitter n-PERT, both cell structures can be produced with only a few adaptations in the entire process sequence because both feature the same front side design: homogeneous n(+) diffused region with low surface concentration, SiO2/SiNx:H passivation, Ni/Cu/Ag plated contacts. Energy conversion efficiencies up to 20.5% (externally confirmed at FhG-ISE Callab) are presented for both cell structures on large area cells together with power-loss analysis and potential efficiency improvements based on PC1D simulations. We demonstrate that the use of a rear emitter n-PERT cell design with Ni/Cu/Ag plated front side contacts enables to reach open-circuit voltage values up to 676mV on 1-2cm n-type CZ Si. We show that rear emitter n-PERT cells present the potential for energy conversion efficiencies above 21.5% together with a strong tolerance to wafer thickness and bulk resistivity. Copyright (c) 2014 John Wiley & Sons, Ltd.
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