Article
Energy & Fuels
Philipp Wagner, Alexandros Cruz, Johann-Christoph Stang, Lars Korte
Summary: The study focuses on achieving low contact resistivity for p-contacts in silicon heterojunction (SHJ) solar cells by using direct aluminum metallization instead of classic n-type transparent conductive oxides. The results show that carefully annealing the aluminum/amorphous silicon contact at moderate temperatures leads to a specific contact resistivity that is significantly lower than its silver/ITO counterpart. The study also highlights the efficiency of hole tunnel-recombination between aluminum and amorphous silicon, leading to improved device performance in terms of fill factor and power conversion efficiency.
IEEE JOURNAL OF PHOTOVOLTAICS
(2021)
Article
Physics, Applied
Jonathan L. Bryan, Joe V. Carpenter, Zhengshan J. Yu, Ashling (Mehdi) Leilaeioun, Jianwei Shi, William Weigand, Kathryn C. Fisher, Zachary C. Holman
Summary: Contacts implemented on the rear side of silicon heterojunction solar cells, such as a-Si:H(i)/a-Si:H(n)/Al and a-Si:H(i)/a-Si:H(p)/Al, demonstrate promising performance in electrical test structures and full-area solar cells. The stability and performance of the contacts are affected by annealing temperature and thickness of doped a-Si:H layers. Transmission electron microscopy and energy-dispersive x-ray spectroscopy analysis help to explain Al-Si interactions at the interfaces and understand the limiting materials properties affecting contact stability.
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2021)
Article
Energy & Fuels
Berkeli Akgayev, Aysegul Sezgin, Mucahit Yilmaz, Veysel Unsur
Summary: In this study, a nickel metal paste with a graphene layer is developed for screen printed Ni contacts in crystalline silicon solar cells. The glass frit transition temperature is adjusted to achieve optimal etching behavior, leading to excellent electrical output parameters. The results demonstrate the success of using this Ni metal paste for improved contacts in solar cells.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2023)
Article
Energy & Fuels
Vaibhav V. Kuruganti, Daniel Wurmbrand, Thomas Buck, Sven Seren, Miro Zeman, Olindo Isabella, Fabian Geml, Heiko Plagwitz, Barbara Terheiden, Valentin D. Mihailetchi
Summary: Although interdigitated back contact (IBC) architecture produces the most efficient solar cells, it is challenging to make them cost-effective and industrially viable. Single-sided atmospheric pressure chemical vapor deposition (APCVD) is investigated as a potential method for fabricating IBC solar cells due to its advantages of reducing thermal budget, simplifying wet bench processing, and eliminating the need for an additional masking layer. Experimental results showed that a full APCVD IBC solar cell achieved a high conversion efficiency of 22.8%, comparable to commercially available full-tube diffused ZEBRA (R) IBC solar cells.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2023)
Article
Physics, Applied
Yuchao Zhang, Li Wang, Daniel Chen, Moonyong Kim, Brett Hallam
Summary: This study investigated the efficiency potential of fully screen-printed PERC solar cells through numerical simulations, revealing significant limitations from carrier recombination losses at the metal/silicon interface. Recommendations for improvements were made to overcome these limitations and achieve higher efficiencies.
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2021)
Article
Energy & Fuels
Matthew Wright, Anastasia Soeriyadi, Brendan Wright, Dmitry Andronikov, Ilia Nyapshaev, Sergey Abolmasov, Alexey Abramov, Brett Hallam
Summary: The study demonstrates the effectiveness of illuminated annealing using high-intensity light to improve the efficiency of industrial n-type silicon heterojunction (SHJ) solar cells, showing significant efficiency enhancements with high-intensity light leading to final efficiencies as high as 24.5%. This technique has the potential to drive reductions in the levelized cost of electricity for SHJ solar cells if tailored to mass production time scales.
IEEE JOURNAL OF PHOTOVOLTAICS
(2022)
Article
Energy & Fuels
Lilan Wen, Lei Zhao, Guanghong Wang, Xiaojie Jia, Xiaohua Xu, Shiyu Qu, Xiaotong Li, Xianyang Zhang, Ke Xin, Jihong Xiao, Wenjing Wang
Summary: The trilayer a-SiOx:H(i) stacked passivation structure was designed for SHJ solar cells on n-type c-Si wafer to improve their fill factor (FF). By depositing a-SiOx:H(i) layers with different oxygen contents using PECVD, highly efficient SHJ solar cells with an average efficiency of 25.37% were achieved. The trilayer passivation scheme demonstrated higher JSC, VOC, and slightly increased FF compared to solar cells with complete a-Si:H passivation layers.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2023)
Article
Energy & Fuels
Abasifreke Ebong, Donald Intal, Sandra Huneycutt, Thad Druffel, Ruvini Dharmadasa, Kevin Elmer, Apolo Nambo
Summary: This study demonstrates the successful metallization of a PERC silicon solar cell using screen-printable copper (Cu) paste. The Cu paste contains antioxidant additives and diffusion inhibitors to prevent oxidation and diffusion of Cu. The Cu-printed cells achieved an efficiency of 19% and showed no Cu diffusion after characterization tests. The long-term stability and effectiveness of the Cu diffusion barrier were also confirmed.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2024)
Article
Energy & Fuels
Nour El Boukortt, Salvatore Patane, Mabrouk Adouane, Rawan AlHammadi
Summary: The ultrathin Cu (In1-xGax) Se2 solar cells with rear surface passivation were optimized using Silvaco-TCAD tools. The study demonstrated that the diversity of carrier transport mechanisms at the heterointerface CdS/CIGS has a significant impact on cell performance. The ultrathin CIGS structure used in the experiment can achieve efficiencies of up to 13%.
Article
Chemistry, Multidisciplinary
Antonio Oliveira, Marco Curado, Jennifer Teixeira, Daniela Tome, Ihsan Caha, Kevin Oliveira, Tomas Lopes, Margarida Monteiro, Andre Violas, Maria Correira, Paulo Fernandes, Francis Deepak, Marika Edoff, Pedro Salome
Summary: A decentralized energy system requires photovoltaic solutions that meet new aesthetic paradigms and address materials shortages. Interface passivation is a strategy to reduce absorber thickness and improve efficiency, but a deeper understanding is needed to bridge the gap between ultra-thin devices and mono-Si. A comparison between a passivated ultra-thin solar cell and a conventional nonpassivated counterpart showed significant differences in charge carrier dynamics, with the passivated device demonstrating lower recombination rates and improved efficiency.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Energy & Fuels
Byungsul Min, Nadine Wehmeier, Till Brendemuehl, Felix Haase, Yevgeniya Larionova, Lasse Nasebandt, Henning Schulte-Huxel, Robby Peibst, Rolf Brendel
Summary: This article reports on recent progress in p-type back junction solar cells with an aluminum front grid and n(+)-type passivating polysilicon on oxide (POLO) contact. The study found that increasing the thickness of the SiNx capping layer can improve the open-circuit voltage of the cells and prevent contact damage.
Article
Energy & Fuels
Dongjin Choi, HyunJung Park, Soohyun Bae, Seung Hyun Shin, Hyebin Han, Bernhard Kloeter, Donghwan Kim, Hae-Seok Lee, Yoonmook Kang
Summary: This study investigates effective contact formation during low-temperature firing with applied current in Si solar cells. By applying a current during firing, contact resistance was reduced and SiNx etching was enhanced, resulting in improved device efficiency.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2022)
Article
Energy & Fuels
Katarzyna Gawlinska-Necek, Robert P. Socha, Pawel Balawender, Maciej K. Stodolny, Bas B. Van Aken, Zbigniew Starowicz, Piotr Panek
Summary: This study investigates the aging behavior of silicon photovoltaic modules with copper-containing electrodes. Thermal cycling (TC) tests show minimal deterioration in electrical parameters, while damp heat (DH) tests result in significant decreases mainly in fill factor (FF) and efficiency (η). The decrease in electrical performance is attributed to copper corrosion caused by products of the decomposed EVA laminating film, as shown by electroluminescence (EL) and X-ray photoelectron spectroscopy (XPS) measurements.
PROGRESS IN PHOTOVOLTAICS
(2021)
Article
Nanoscience & Nanotechnology
Tomas S. Lopes, Jessica de Wild, Celia Rocha, Andre Violas, Jose M. Cunha, Jennifer P. Teixeira, Marco A. Curado, Antonio J. N. Oliveira, Jerome Borme, Gizem Birant, Guy Brammertz, Paulo A. Fernandes, Bart Vermang, Pedro M. P. Salome
Summary: The study demonstrated the simultaneous implementation of potassium fluoride (KF) post-deposition treatment (PDT) and a rear interface passivation strategy on ultrathin Cu(In,Ga)Se-2 (CIGS) solar cells for the first time. Electrical measurements and simulations suggested that under specific conditions, devices with only KF-PDT treatment may outperform those with rear interface passivation alone. By combining KF-PDT and rear interface passivation, there was a significant enhancement in open-circuit voltage and reduction in recombination losses, leading to improved charge carrier lifetime in the studied devices.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Energy & Fuels
Andreas Lorenz, Markus Klawitter, Michael Linse, Linda Ney, Sebastian Tepner, Sebastian Pingel, Milad Salimi Sabet, Julius Reiner, Katrin Oehrle, Roland Greutmann, Julius Roeth, Matthias Drews, Kazuo Muramatsu, Sen-ichi Ikarashi, Florian Clement
Summary: The study demonstrates the fabrication of bifacial silicon heterojunction solar cells using rotary screen printed front- and rear-side metallization, achieving high efficiency and low silver consumption. Through a newly developed screen simulation method and detailed analysis, the accuracy of the metallization process is ensured.
Article
Energy & Fuels
Fabian Fertig, Sebastian Nold, Nico Woehrle, Johannes Greulich, Ingrid Haedrich, Karin Krauss, Max Mittag, Daniel Biro, Stefan Rein, Ralf Preu
PROGRESS IN PHOTOVOLTAICS
(2016)
Article
Energy & Fuels
P. Rothhardt, S. Meier, R. Hoenig, A. Wolf, D. Biro
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2016)
Article
Electrochemistry
Oliver Fitz, Christian Bischoff, Manuel Bauer, Harald Gentischer, Kai Peter Birke, Hans-Martin Henning, Daniel Biro
Summary: This study investigates the reaction mechanisms during cycling of aqueous rechargeable Zn//MnO2 batteries through different acidic electrolyte compositions and their pH behavior, showing the significance of pH-relevant ions and zinc hydroxide sulfate precipitation. The innovative approach of coupled cyclic voltammetry and pH measurements provides insights into the redox peaks and chemical reactions during cycling, contributing to the debate of RMs in ARZIBs and other aqueous battery chemistries.
Article
Electrochemistry
Mathias Drews, Jan Buettner, Manuel Bauer, Junaid Ahmed, Rajib Sahu, Christina Scheu, Severin Vierrath, Anna Fischer, Daniel Biro
Summary: This study presented lithium-ion battery full-cells based on spruce-derived hard carbon anodes and an electrochemical pre-lithiation method, with a detailed analysis of full-cell operation and lithiation state. Despite the similarities in physical and electrochemical properties with previous biomass-derived hard carbon anodes, the low initial coulombic efficiencies remain a major challenge. In-situ electrochemical pre-lithiation improved performance significantly, leading to increased capacities, cycle life, and first cycle coulombic efficiency.
Article
Materials Science, Multidisciplinary
Mathias Drews, Tobias Troetschler, Manuel Bauer, Apurupa Guntupalli, Witali Beichel, Harald Gentischer, Rolf Muelhaupt, Benjamin Kerscher, Daniel Biro
Summary: In this work, a cationic polymer is used as a key component of gel polymer electrolytes (GPE) for lithium-ion batteries. The GPE exhibits good electrolyte retaining ability, high ionic conductivity, excellent oxidative stability, and good cycling performance.
ACS APPLIED POLYMER MATERIALS
(2022)
Article
Electrochemistry
Julia Pross-Brakhage, Oliver Fitz, Christian Bischoff, Daniel Biro, Kai Peter Birke
Summary: The energy transition relies on photovoltaic powerplants and efficient use of photovoltaic power requires batteries. The demand for renewable energy storage presents new challenges in terms of cost, resource availability, and safety. This paper discusses the evolution of zinc and manganese dioxide-based aqueous battery technologies and highlights the competitive advantages of rechargeable Zn-MnO2 batteries (ZMB) for stationary applications. It also provides a perspective on current challenges and future research concepts. This work aims to classify the current state of research on ZMB and explore its potential within the Battery Ecosystem by discussing key parameters such as safety, cost, cycle life, energy and power density, material abundancy, sustainability, modelling, and cell/module development.
Article
Electrochemistry
Witali Beichel, Julian Skrotzki, Petra Klose, Christian Njel, Burkhard Butschke, Stephan Burger, Lili Liu, Ralf Thomann, Yi Thomann, Daniel Biro, Simon Thiele, Ingo Krossing
Summary: A study found that Li electrodes treated with the phosphoric-acid derivative HBFEP exhibit self-healing ability and an extended cycle lifetime. This treatment method shows promising performance in Li-Li symmetrical cells, potentially enhancing the rechargeability of Li electrodes.
BATTERIES & SUPERCAPS
(2022)
Article
Electrochemistry
Oliver Fitz, Stefan Ingenhoven, Christian Bischoff, Harald Gentischer, Kai Peter Birke, Dragos Saracsan, Daniel Biro
Summary: The research focused on the binder types and mixing ratio for the positive electrode fabrication of aqueous rechargeable Zn//MnO2 batteries. It was found that binders using aqueous solvents performed better under certain electrolyte conditions. The study also looked at how to decrease the passive material share while maintaining battery performance.
Article
Chemistry, Physical
L. Pitta Bauermann, L. Mesquita, C. Bischoff, M. Drews, O. Fitz, A. Heuer, D. Biro
JOURNAL OF POWER SOURCES ADVANCES
(2020)
Article
Chemistry, Multidisciplinary
Mathias Drews, Sebastian Tepner, Peter Haberzettl, Harald Gentischer, Witali Beichel, Matthias Breitwieser, Severin Vierrath, Daniel Biro
Article
Electrochemistry
Christian Friedrich Bischoff, Oliver Sebastian Fitz, Jordan Burns, Manuel Bauer, Harald Gentischer, Kai Peter Birke, Hans-Martin Henning, Daniel Biro
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2020)
Article
Electrochemistry
Christian Bischoff, Oliver Fitz, Christian Schiller, Harald Gentischer, Daniel Biro, Hans-Martin Henning
Article
Energy & Fuels
Sebastian Meier, Stefan Maier, Carsten Demberger, Andreas Wolf, Daniel Biro, Stefan W. Glunz
Proceedings Paper
Energy & Fuels
M. Pospischil, M. Klawitter, M. Kuchler, M. Jahn, R. Efinger, R. Schwarz, L. Wende, M. Koenig, F. Clement, D. Biro
PROCEEDINGS OF THE SIXTH WORKSHOP ON METALLIZATION AND INTERCONNECTION FOR CRYSTALLINE SILICON SOLAR CELLS
(2016)
Proceedings Paper
Energy & Fuels
Matthieu Ebert, Tobias Fellmeth, Tobias Doersam, Florian Clement, Daniel Biro, Maike Wiesenfarth, Ulrich Eitner
11TH INTERNATIONAL CONFERENCE ON CONCENTRATOR PHOTOVOLTAIC SYSTEMS (CPV-11)
(2015)