One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+center

Use of Perfluorocarboxylic Acids To Trick Cytochrome P450BM3 into Initiating the Hydroxylation of Gaseous Alkanes

(2011) Norifumi Kawakami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tuning a P450 Enzyme for Methane Oxidation

(2011) Felipe E. Zilly et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

EPR,1H and2H NMR, and Reactivity Studies of the Iron–Oxygen Intermediates in Bioinspired Catalyst Systems

(2011) Oleg Y. Lyakin et al.   INORGANIC CHEMISTRY

Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions

(2011) Irene Prat et al.   Nature Chemistry

Efficient water oxidation catalysts based on readily available iron coordination complexes

(2011) Julio Lloret Fillol et al.   Nature Chemistry

Synthesis, Structure, and Reactivity of an Iron(V) Nitride

(2011) J. J. Scepaniak et al.   SCIENCE

cis-Dihydroxylation of Alkenes with Oxone Catalyzed by Iron Complexes of a Macrocyclic Tetraaza Ligand and Reaction Mechanism by ESI-MS Spectrometry and DFT Calculations

(2010) Toby Wai-Shan Chow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics

(2010) J. Rittle et al.   SCIENCE

Olefin-Dependent Discrimination between Two Nonheme HOFeVO Tautomeric Species in Catalytic H2O2Epoxidations

(2009) Anna Company et al.   CHEMISTRY-A EUROPEAN JOURNAL

Broken-Symmetry DFT Spin Densities of Iron Nitrosyls, Including Roussin’s Red and Black Salts: Striking Differences between Pure and Hybrid Functionals

(2009) Kathrin H. Hopmann et al.   JOURNAL OF PHYSICAL CHEMISTRY B

EPR Spectroscopic Trapping of the Active Species of Nonheme Iron-Catalyzed Oxidation

(2009) Oleg Y. Lyakin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Determination by High-Frequency and -Field EPR of Zero-Field Splitting in Iron(IV) Oxo Complexes: Implications for Intermediates in Nonheme Iron Enzymes

(2008) J. Krzystek et al.   INORGANIC CHEMISTRY

Axial Ligand Effects on the Geometric and Electronic Structures of Nonheme Oxoiron(IV) Complexes

(2008) Timothy A. Jackson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Versatility of biological non-heme Fe(II) centers in oxygen activation reactions

(2008) Elena G Kovaleva et al.   Nature Chemical Biology