Journal
PROCEEDINGS OF THE COMBUSTION INSTITUTE
Volume 33, Issue -, Pages 367-374Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.proci.2010.05.003
Keywords
1-Pentanol; Alcohol; Flame speed; Jet-stirred reactor; Kinetic modeling
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1-Pentanol is among the possible alcohols usable as an alternative to conventional gasoline and diesel fuels. In order to better understand the combustion characteristics of 1-pentanol, this study presents new experimental data for 1-pentanol in two complementary experimental configurations. Stable species concentration profiles were measured in a jet-stirred reactor (JSR) at 10 atm over a range of equivalence ratios and temperatures. Laminar flame speeds of 1-pentanol-air premixed laminar flame were measured at 1 atm and 423 K for equivalence ratios of 0.7-1.4. The oxidation of 1-pentanol in these experimental configurations was modeled using an extended detailed chemical kinetic reaction mechanism (2099 reactions involving 261 species) derived from a previously proposed scheme for the oxidation of methanol-, ethanol-, and 1-butanol-based fuels. The proposed mechanism shows good agreement with the present experimental data. Reaction path analyses were conducted to interpret the JSR results. (C) 2010 The Combustion Institute. Published by Elsevier Inc. All rights reserved.
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