3.9 Article

Performances of a Polymeric Intumescent Flame Retardant in Styrene Butadiene Rubber

Journal

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING
Volume 51, Issue 10, Pages 1018-1023

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/03602559.2012.689046

Keywords

Polymeric intumescent flame retardant; Properties; Styrene butadiene rubber

Funding

  1. National Natural Science Foundation of China [21174106]
  2. Shanghai Key Lab of Electric Insulation and Thermal Aging
  3. Natural Science Research Fund of Anhui Province [KJ2008A070]

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A polymeric intumescent flame retardant, PPVAM, was synthesized by the reaction of polyvinyl alcohol with phosphoric acid, and further with melamine. Flame-retardant properties of PPVAM in styrene butadiene rubber (SBR) were evaluated by using LOI and UL-94 test, and thermal decomposition and char of SBR/PPVAM composites were investigated by thermogravimetry, Muffle and SEM. The results indicate that SBR/PPVAM composites on burning can produce a multi-celluar char, resulting in good flame-retardant properties. The SBR/PPVAM composites after 70 degrees C water treatment for 7 days still maintain good flame retardancy. Moreover, mechanical properties of SBR/PPVAM composites are studied.

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