Journal
POLYMER JOURNAL
Volume 44, Issue 7, Pages 718-723Publisher
NATURE PUBLISHING GROUP
DOI: 10.1038/pj.2012.12
Keywords
alicyclic dianhydride; polyimide; solubility; thermal properties; transparency
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Funding
- National Natural Science Foundation of China [50403025]
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The asymmetrical alicyclic dianhydride 3,4-dicarboxy-1,2,3,4-tetrahydro-6-methyl-1-naphthalene succinic dianhydride (MTDA, II) was synthesized from 4-methylstyrene and maleic anhydride under nitric oxide catalysis with a yield >70%. A series of semi-alicyclic polyimides (PIs) (PI-IIa similar to PI-IId) were prepared by a one-step high temperature polycondensation procedure from MTDA and various aromatic diamines. For comparison, another series of PIs (PI-I-a similar to PI-I-d) were prepared from the analogous dianhydride 3,4-dicarboxy-1,2,3,4-tetrahydro-1-naphthalene succinic dianhydride (TDA, I) and the same diamines. The asymmetrical molecular structure of MTDA endowed the derived PIs with good solubilities in common solvents and high optical transparencies in the ultraviolet and visible light regions by decreasing the intramolecular or intermolecular interactions of the polymer chains. The flexible and tough PI films exhibited good thermal stability up to 400 degrees C and showed glass transition temperatures in the range of 204-271 degrees C. The PI films exhibited good optical transparency with transmittances >80% at 400 nm, a cut-off wavelength <300nm and a refractive index <1.54. Polymer Journal (2012) 44, 718-723; doi: 10.1038/pj.2012.12; published online 7 March 2012
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