Journal
POLYMER JOURNAL
Volume 40, Issue 7, Pages 622-628Publisher
NATURE PUBLISHING GROUP
DOI: 10.1295/polymj.PJ2008044
Keywords
phenolic resin; novolac; addition-condensation; friedel-crafts polymerization; fluorine-containing polymer; heat resistant material
Categories
Ask authors/readers for more resources
We report the synthesis of fluorine-containing poly(arylenemethylene)s as a new heat-resistant denatured phenolic resin by addition-condensation or Friedel-Crafts polymerization. In the case of polymerization of 2,2-bis(4-methoxyphenyl)hexafluoropropane (1a) with an equimolar amount of formaldehyde, the polymerization proceeded homogeneously to give the polymer 2a (M-n 8,200, M-w/M-n 2.1) in 71% yield. The FT-IR, H-1 NMR and C-13 NMR spectra of 2a revealed that it had arylene-methylene units on the polymer backbone. The polymerizations of 3-(trifluoromethoxy)benzyl bromide (1b) or 4(trifluoromethoxy)benzyl bromide (1c) via the Friedel-Crafts polymerization using aluminum chloride as a catalyst produced the polymer 2b and 2c in 38% and 16% yield, respectively. From the TGA, the temperatures at 10% loss in weight (T-10) of 2a and 2c were found to be 425 and 298 degrees C, respectively. As compared to the non-fluorinated poly(arylenemethylene) derived from 2,2-bis(4-methoxyphenyl)propane-formaldehyde polymer (2d) (T-10 = 397 degrees C, 2a showed high thermostability in terms of the temperature of T-10. The results indicated that the thermal stability of poly(arylenernethylene) s was enhanced by the introduction of fluorine moieties in the polymer.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available