4.7 Article

The thermal and dielectric properties of high performance cyanate ester resins/microcapsules composites

Journal

POLYMER DEGRADATION AND STABILITY
Volume 96, Issue 1, Pages 84-90

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.polymdegradstab.2010.10.013

Keywords

High performance polymer; Thermal properties; Dielectric properties

Funding

  1. China Postdoctoral Science Foundation [20080440165]
  2. Third Batch of Special Sustentation of China Postdoctoral Science Foundation [599]
  3. Jiangsu Provincial Postdoctoral Science Research Sustentation Fund [0802019B]
  4. National Natural Science Foundation of China [50903058]
  5. Provincial Natural Science Foundation of Jiangsu [BK2009124]

Ask authors/readers for more resources

Novel high performance bisphenol A dicyanate ester (BADCy) resins/poly(urea-formaldehyde) microcapsules filled with epoxy resins (MCEs) composites have been prepared. The effects of different contents of MCEs on the thermal and dielectric properties of cured BADCy were investigated using dynamic mechanical analyzer (DMA), thermalgravimetric analyzer (TGA) and broadband dielectric analyzer. The dielectric properties of BADCy/MCEs treated in hot water and hot air were also discussed. The morphologies of BADCy/MCEs composites were characterized by scanning electron microscopy (SEM). Results indicate that the appropriate content of MCEs can improve or maintain the thermal stability, the low dielectric constant and dielectric loss of cured BADCy mainly owing to higher conversion of cyanate ester (-OCN) groups. After aged in hot water and hot air, respectively, BADCy/MCEs composites with small content of MCEs can retain the low dielectric constant and dielectric loss. (C) 2010 Elsevier Ltd. All rights reserved.

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