4.7 Article

Living polymerization of arylisocyanide initiated by the phenylethynyl palladium(II) complex

Journal

POLYMER CHEMISTRY
Volume 5, Issue 22, Pages 6435-6438

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4py01023j

Keywords

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Funding

  1. National Natural Scientific Foundation of China [21104015, 21172050, 21371043, 51303044, 21304027]
  2. Natural Scientific Foundation of Anhui Province [1408085QE80]
  3. Thousand Young Talents Program

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A family of air-stable phenylethynyl palladium complexes was unexpectedly found to initiate the polymerization of phenyl isocyanide in a living/controlled chain growth manner, affording well-defined, stereoregular poly(phenyl isocyanide)s in high yield with controlled molecular weights and narrow molecular weight distributions.

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