Journal
POLYMER CHEMISTRY
Volume 5, Issue 20, Pages 6097-6107Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4py00663a
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Funding
- National Basic Research Program of China (973 program) [2012CB025903]
- National Natural Science Foundation of China [51210004, 50873040]
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The sulfonated polyphenylsulfone (SPPSU) membranes with different degrees of sulfonation (DS) were prepared for fabricating low-cost and high-performance ionic polymer-metal composite (IPMC) actuators. The properties of SPPSU ion exchange membranes and the electromechanical performance of resulting SPPSU actuators can be manipulated by controlling their DS. As the DS of SPPSU membranes increases, their ion exchange capacity (IEC), water uptake and ion conductivity increase accordingly, whereas the hydrated mechanical properties (strength and modulus) decrease. The SPPSU membrane with the highest DS (SPPSU4) shows much higher IEC and water uptake, and slightly lower ion conductivity than those of the traditional Nafion membrane. Among the prepared IPMC actuators, the SPPSU4 actuator performs the best in the bending deformation under the electric stimulus. The maximum bending strain (MBS) of the SPPSU4 actuator is comparable to that of the Nafion actuator coupled with several times faster bending response at 3 V DC voltage. Compared with the Nafion system, the SPPSU4 actuator increases approximately twice at MBS under a sinusoidal voltage of 3 V at 1 Hz. This greatly enhanced actuation performance indicates that the SPPSU is a candidate to substitute Nafion in the field of IPMC actuators.
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