Journal
POLYMER CHEMISTRY
Volume 2, Issue 10, Pages 2179-2182Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1py00203a
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Funding
- National Key Basic Research Program of China (973) [2009CB930600]
- National Natural Science Foundation of China [60876010, 20774043, 20704023, 20974046]
- Ministry of Education of China [208050]
- Natural Science Foundation of Jiangsu Province [BK2008053, 10KJB510013, SJ209003]
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C-H bond functionalization offers a chance to develop a new concept of polymerization. In this article, a family of diarylfluorene-based p-conjugation-interrupted polymers (CIPs) with nonlinear or hyperbranched frameworks have been explored by BF3 center dot Et2O-mediated Friedel-Crafts polymerization of AB, AB(2) and AB(4)-type tertiary alcohol monomers at room temperature. Their chemical structures and optoelectronic properties have been characterized and the existence of strong intermolecular pi-stacked aggregates have been observed. CIP semiconductors afford a new platform to explore novel functionality of organic devices in organic electronics or spinelectronics.
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