Journal
POLYHEDRON
Volume 155, Issue -, Pages 425-432Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2018.08.070
Keywords
Thiocyanate; Hydrazones; Co(III) and Co(II) complexes; X-ray; Magnetic properties
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Funding
- Ministry of Education, Science and Technological development of the Republic of Serbia [OI 172055]
- Slovenian Research Agency [P-0175, P2-0348]
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Octahedral Co(III) complexes with heteroaromatic hydrazones ((E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium chloride and (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide) and tetraisothiocyanato Co(II) complex anions have been synthesized, characterized by elemental analysis, IR and NMR spectroscopy, single-crystal X-ray diffraction and magnetic measurements. NMR spectroscopy showed that octahedral Co(III) complex cations of both compounds are stable in DMSO solution. Measured effective magnetic moments, which completely originates from complex anion [Co(NCS)(4)](2-) are practically constant and very close to the expected value for Co2+ ion with spin S = 3/2 and completely quenched orbital angular momentum. Co(III) ions in octahedral complex cations are in a low spin magnetic state with S = 0 and do not contribute to the magnetic signal. (C) 2018 Elsevier Ltd. All rights reserved.
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