Journal
CHEMICAL SCIENCE
Volume 6, Issue 1, Pages 777-781Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4sc01317d
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Funding
- National Sciences and Engineering Research Council (NSERC)
- Canada Research Chair
- Royal Society
- University of Liverpool
- Queen's University
- EPSRC [EP/K039687/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K039687/1] Funding Source: researchfish
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We have devised a highly regio- and enantioselective iridium-catalyzed allylic amination reaction with the sulfur-stabilized aza-ylide, S,S-diphenylsulfilimine. This process provides a robust and scalable method for the construction of aryl-, alkyl- and alkenyl-substituted C-chiral allylic sulfilimines, which are important functional groups for organic synthesis. Additionally, the combination of the allylic amination with an in situ deprotection of the sulfilimine constitutes a convenient one-pot protocol for the construction of chiral nonracemic primary allylic amines.
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