4.7 Article

Nickel-copper hybrid electrodes self-adhered onto a silicon wafer by supersonic cold-spray

Journal

ACTA MATERIALIA
Volume 93, Issue -, Pages 156-163

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2015.04.012

Keywords

Silicon solar cell; Nickel-copper electrode; Supersonic cold spraying; Contact resistivity; Specific resistivity

Funding

  1. Global Frontier Program through the Global Frontier Hybrid Interface Materials (GFHIM) of the National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning [2013M3A6B1078879]
  2. Industrial Strategic Technology Development Program - Ministry of Knowledge Economy (MKE, Korea) [10045221]
  3. Deanship of Scientific Research at King Saud University [RGP-089]
  4. [NRF-2013R1A2A2A05005589]
  5. National Research Council of Science & Technology (NST), Republic of Korea [KIER2-3] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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High-performance electrodes are fabricated through supersonic spraying of nickel and copper particles. These electrodes yield low specific resistivities, comparable to electrodes produced by screen-printed silver paste and light-induced plating. The appeal of this fabrication method is the low cost of copper and large area scalability of supersonic spray-coating techniques. The copper and nickel electrode was fabricated in the open air without any pre- or post-treatment. The spray-coated copper nickel electrode was characterized by optical microscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction, and energy dispersive spectroscopy. Although both SEM and TEM images confirmed voids trapped between flattened particles in the fabricated electrode, this electrode's resistivity was order 10(-6) Omega cm, which is comparable to the bulk value for pure copper. (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

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