Article
Chemistry, Physical
Venkatramana Losetty, M. Raveendra, C. Hazarathaiah Yadav, U. Chalapathi, Si-Hyun Park
Summary: This study experimentally measured the density and speed of sound of binary mixtures of benzylalcohol with methyl acetoacetate, ethyl acetoacetate, and allyl acetoacetate. The data was used to calculate various properties such as excess molar volume, isentropic compressibility, and excess speed of sound. The results indicate the presence of hydrogen bonds and their influence on the properties of the mixtures.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Multidisciplinary
Yeongseo An, Puranjan Chatterjee, Pranjali Naik, Sayak Banerjee, Wenyu Huang, Igor I. Slowing, Vincenzo Venditti
Summary: Substrate-support interactions play an important role in the hydrogenation of phenolic compounds. Titanium oxide has the ability to form hydrogen bonds with the substrate and mediate the addition of activated hydrogens.
Article
Instruments & Instrumentation
Harumi Sato, Yusuke Morisawa, Satoshi Takaya, Yukihiro Ozaki
Summary: Inter- and intramolecular hydrogen bonding in a PVPh 30%/PMMA 70% blend were investigated using near-infrared (NIR) and infrared (IR) spectroscopy, revealing temperature-dependent changes in the hydrogen bonding. The study demonstrated that different types of hydrogen bonding exhibit distinct spectral features at different temperatures.
APPLIED SPECTROSCOPY
(2022)
Article
Environmental Sciences
Yifan Liu, Nana Li, Cong Du, Yue Wang, Kunyu He, Hao Zheng, Zhijing Xue, Qin Chen, Xiaoyun Li
Summary: This study investigated the sorption/desorption behaviors of three pharmaceutical contaminants (PCs) on three Oxygen-rich nanoparticles. It was found that different hydrogen bonds, especially charge-assisted hydrogen bonds, played a crucial role in the sorption and desorption of PCs on the nanomaterials. The stronger charge-assisted hydrogen bonds caused significant desorption hysteresis and better immobilization of PCs on the nanomaterials.
ENVIRONMENTAL POLLUTION
(2023)
Article
Engineering, Biomedical
Jeehee Lee, Eunsook Park, Kyueui Lee, Mikyung Shin, Soohyeon Lee, Miguel Angel Moreno-Villaecija, Haeshin Lee
Summary: Plants release phenolic molecules for protection, and we designed an adhesive sealant inspired by the phenol-saccharide interactions in plant defense systems. By screening different saccharides, the O-acetyl group in glucomannan showed strong binding with tannic acid. This interaction exhibited pH and temperature sensitivities and could be used to prepare materials of various dimensions for printing techniques.
ACTA BIOMATERIALIA
(2023)
Article
Nanoscience & Nanotechnology
Bo-Hyun Kim, Wontae Kim, Taemin Kim, Byoung Min Ko, Soon-Jik Hong, Kangtaek Lee, Jinsang Kim, Sung-Ho Song, Sunjong Lee
Summary: This study demonstrates that a fluorophore can enhance its fluorescence quantum yield through hydrogen bonding, providing a new strategy for fluorophore design. Additionally, the fluorophore embedded in a polymer matrix can selectively detect specific gases, which is crucial for the development of fluorescence sensing systems.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Polymer Science
Dorothee Ehrhardt, Jessica Mangialetto, Kurt Van Durme, Bruno Van Mele, Niko Van den Brande
Summary: The applicability of high-modulus poly(methacrylate) networks with reversible Diels-Alder crosslinks as self-healing coatings for outdoor applications is evaluated. The stability of the polymer network is assessed using spectroscopic techniques, thermogravimetric analysis, and kinetic simulations before and after accelerated UV-ageing. The reversibility of the Diels-Alder bonds is confirmed by differential scanning calorimetry. Dynamic mechanical analysis demonstrates that both pristine and UV-aged reversible networks maintain their structural integrity and exhibit self-healing of micro-defects within a temperature range of -80 degrees C to 120 degrees C, restoring their thermomechanical properties. Kinetic modelling is used to simulate the effect of temperature on the Diels-Alder conversion during a typical day cycle for photovoltaic modules. The modelling results show that the total Diels-Alder conversion remains high, ensuring mechanical robustness by maintaining a high crosslink density during high temperature exposure and temperature cycling, indicating the thermal stability and potential use of these materials in outdoor photovoltaic applications.
POLYMER DEGRADATION AND STABILITY
(2022)
Article
Spectroscopy
Mohammad Pabel Kabir, Yoelvis Orozco-Gonzalez, Gary Hastings, Samer Gozem
Summary: Cluster and continuum solvation computational models were used to study the effect of hydrogen bonding on the vibrational modes of lumiflavin. The v(C2-O) and v(C4-O) modes were found to be sensitive to direct hydrogen-bonding interactions. The 6-31+G* basis set was adequate for the system, with limited benefits to considering larger basis sets. Accurate simulation of FTIR band intensities requires a model that accounts for long-range electrostatic effects.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2021)
Article
Crystallography
Guangchuan Ou, Qiong Wang, Qiang Zhou, Xiaofeng Wang
Summary: Five host-guest trimesic acid-based hydrogen-bond framework compounds with different guests were obtained through co-crystallization and characterized. These compounds showed different morphologies including two-dimensional, three-dimensional, and one-dimensional chain structures.
Article
Polymer Science
Wei-Ting Du, Shiao-Wei Kuo
Summary: In this study, we synthesized a series of random copolymers of methyl methacrylate (MMA) and N-hydroxyphenylmaleimide (HPMI) using free radical copolymerization. These copolymers exhibited high glass transition temperatures (T-g) due to the strong intermolecular hydrogen bonding between the PMMA and PHPMI segments. The results from various analytical techniques confirmed the chemical structures, thermal properties, hydrogen bonding interactions, and sequence distributions of these copolymers.
EUROPEAN POLYMER JOURNAL
(2022)
Article
Chemistry, Applied
Yixiang Zhao, Jie Wang, Haitong Liu, Zilin Yi, Zihan Shan, Yaru Ni, Liang Fang, Chunhua Lu, Zhongzi Xu
Summary: In this paper, hindered phenol/epoxy microspheres were prepared by direct curing in an emulsion containing montmorillonite. The presence of hindered phenol on the microsphere surface led to the formation of interfacial hydrogen bonds between microspheres and waterborne polyurethane. The optimal formulation of microspheres was found to be EAM1075 (10:7:5 ratio of epoxy, AO-80, and MMT) with a particle size of 20-30 μm, which showed improved damping capacity and broadened damping temperature range.
PROGRESS IN ORGANIC COATINGS
(2023)
Article
Biochemistry & Molecular Biology
Stefanos Tsigoias, Constantine Kouderis, Agni Mylona-Kosmas, Angelos G. Kalampounias
Summary: Fourier-transform infrared (FTIR) spectra were used to study the effect of concentration and temperature on intermolecular hydrogen bonding in isopentyl alcohol dissolved in carbon tetrachloride. The study involved dilute isopentyl alcohol/CCl4 solutions at various concentrations and temperatures. The results were analyzed using decomposition and computational methodologies to gain quantitative information about the hydrogen bonding behavior.
Article
Thermodynamics
Lisette M. J. Sprakel, Boelo Schuur
Summary: Renewable phenol can be obtained from pyrolytic bio-oil, however, to utilize it in the production of polycarbonates, upgrading and separating intermediate products and phenol is necessary. Research has shown that extraction of phenol from low concentration aqueous streams can be achieved through liquid-liquid extraction, with the interaction being based on hydrogen bonding instead of proton transfer. Increasing phenol to extractant ratio weakens the primary hydrogen bond, affecting the distribution ratios of phenol in the process.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2021)
Article
Chemistry, Multidisciplinary
Wenping Kang, Yu Bao, Hailong Wang, Nanpu Cao, Shuxun Cui
Summary: Polymethyl methacrylate (PMMA), a material widely used in medicine and engineering, possesses contradictory properties of good hydrophilicity and water insolubility. By studying the interactions between PMMA and water using atomic force microscopy (AFM)-based single-molecule force spectroscopy (SMFS), it has been found that PMMA can form hydrogen bonds with water molecules, affecting its elasticity and hydration. These findings provide insights into the mechanism of PMMA-water interactions at the molecular level, aiding in the regulation of PMMA's mechanical properties.
CHINESE JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Applied
Robin Nilsson, Martina Olsson, Gunnar Westman, Aleksandar Matic, Anette Larsson
Summary: This study investigated the effects of side chain structures on the glass transition temperature and water interactions in cellulose esters. The results showed that the glass transition temperature decreased with increased side chain length, and the solubility and penetration of water in the cellulose esters decreased as well.
CARBOHYDRATE POLYMERS
(2022)
Article
Engineering, Electrical & Electronic
P. Sivagurunathan, S. R. Gibing
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2016)
Article
Engineering, Electrical & Electronic
S. R. Gibin, P. Sivagurunathan
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2017)
Article
Engineering, Electrical & Electronic
P. Sivagurunathan, S. R. Gibin
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2016)
Review
Chemistry, Multidisciplinary
P. Sivagurunathan, P. Hajasharif
ARABIAN JOURNAL OF CHEMISTRY
(2016)
Article
Chemistry, Multidisciplinary
M. S. Manjunath, P. Sivagurunathan, J. Sannappa
E-JOURNAL OF CHEMISTRY
(2009)
Article
Chemistry, Physical
P. Sivagurunathan, P. Hajasharif
JOURNAL OF MOLECULAR LIQUIDS
(2010)
Article
Chemistry, Inorganic & Nuclear
D. Ramarajan, P. Sivagurunathan
JOURNAL OF SOLID STATE CHEMISTRY
(2011)
Article
Engineering, Electrical & Electronic
D. Ramarajan, P. Sivagurunathan, Qingfeng Yan
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2012)
Article
Chemistry, Physical
F. Liakath Ali Khan, P. Sivagurunathan
PHYSICS AND CHEMISTRY OF LIQUIDS
(2008)
Article
Spectroscopy
K. Dharmalingam, K. Ramachandran, P. Sivagurunathan, G. M. Kalamse
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2008)
Article
Polymer Science
K. Dharmalingam, K. Ramachandran, P. Sivagurunathan, B. Prabhakar Undre, P. W. Khirade, S. C. Mehrotra
JOURNAL OF APPLIED POLYMER SCIENCE
(2008)
Article
Engineering, Multidisciplinary
K. Dharmalingam, K. Ramachandran, P. Sivagurunathan, B. Prabhakar Undre, P. W. Khirade, S. C. Mehrotra
JOURNAL OF APPLIED SCIENCE AND ENGINEERING
(2009)
Article
Physics, Multidisciplinary
F. Liakath Ali Khan, P. Sivagurunathan, J. As-Har
INDIAN JOURNAL OF PURE & APPLIED PHYSICS
(2008)
Article
Physics, Multidisciplinary
F. Liakath Ali Khan, P. Sivagurunathan, J. Asghar
INDIAN JOURNAL OF PURE & APPLIED PHYSICS
(2008)