4.8 Article

Magnetic Frustration in Iridium Spinel Compound CuIr2S4

Journal

PHYSICAL REVIEW LETTERS
Volume 112, Issue 8, Pages -

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AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.112.087203

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We demonstrate via a muon spin rotation experiment that the electronic ground state of the iridium spinel compound CuIr2S4 is not the presumed spin-singlet state but a novel paramagnetic state, showing a quasistatic spin glasslike magnetism below similar to 100 K. Considering the earlier indication that IrS6 octahedra exhibit dimerization associated with the metal-to-insulator transition below 230 K, the present result suggests that a strong spin-orbit interaction may be playing an important role in determining the ground state that accompanies magnetic frustration.

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