Journal
PHYSICAL REVIEW B
Volume 87, Issue 1, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.87.014408
Keywords
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Funding
- Swedish Research Council (VR)
- Goran Gustafsson Foundation
- Swedish Foundation for International Cooperation in Research and Higher Education (STINT)
- Russian Foundation for Basic Research
- Ministry of Education and Science of Russia [14.A18.21.0889]
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Due to its polymorphism, Mn2FeSbO6 can be synthesized at high pressures and temperatures as a ferrimagnetic ilmenite or an antiferromagnetic perovskite. The structural phase transformation is discussed in detail, and magnetic structures are proposed for both phases. The high-pressure Mn2FeSbO6 polymorph is a rare example of A(2)B'B '' O-6 perovskite with solely Mn cations on the A site. Fe and Sb cations are ordered on the B sites. Theoretical calculations for the perovskite phase suggest a complex magnetic structure, holding an electronic polarization. DOI: 10.1103/PhysRevB.87.014408
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