Korringa-like relaxation in the high-temperature phase of A-site ordered YBaMn2O6

We report on high-temperature electron spin resonance studies of A-site ordered YBaMn2O6 and disordered Y0.5Ba0.5MnO3. In the disordered sample we find that the linewidth is governed by spin-spin relaxation processes as in many other manganite systems. In contrast we find a Korringa-like spin relaxation with a slope of about 1Oe/K above the charge-ordering transition and extending up to 930 K in the metal ordered YBaMn2O6 samples. A Korringa law is a clear feature of a truly metallic state, pointing to an unconventional high-temperature phase of these ordered manganites. In agreement with the electron spin resonance (ESR) intensity this suggests that in the metallic high-temperature phase the ESR signal stems from Mn4+ core spins which relax via the quasidelocalized e(g) electrons.