Article
Chemistry, Multidisciplinary
Jes K. Larsen, Kostiantyn Sopiha, Clas Persson, Charlotte Platzer-Bjorkman, Marika Edoff
Summary: This contribution investigates the stable and metastable phases forming in CuInS2 (CIS) thin films, which has gained renewed interest due to its potential application in tandem solar cells. The study utilizes a combined theoretical and experimental approach, including ab initio calculations, X-ray diffraction (XRD) patterns, and Raman spectra analysis. Multiple CIS structures with different lattices are identified, and their XRD/Raman patterns are shown to have overlapping features. Thin films with different compositions are synthesized, and it is found that several CIS polymorphs are formed. Additionally, CuIn5S8 and NaInS2 compounds accommodating In-excess are found alongside the CIS polymorphs. The study emphasizes the importance of tight composition control for stabilizing the metastable polymorphs.
Article
Chemistry, Physical
Niklas Humberg, Qinmin Guo, Thomas Bredow, Moritz Sokolowski
Summary: This study investigates the formation of self-assembled aggregates and domains of quinacridone on epitaxial KCl layers on the Ag(100) surface. The results show that when KCl layers do not cover the complete Ag surface, the QA molecules diffuse off the KCl islands and adsorb on the bare Ag surface instead. On the other hand, when the KCl layers completely cover the Ag surface, the growth of QA depends on the thickness of the KCl layer. Ordered linear chains and compact islands of these chains can be formed on thin KCl layers, while only the nucleation of three-dimensional QA clusters occurs on thicker KCl films.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Nanoscience & Nanotechnology
Tingfeng Song, Florencio Sanchez, Ignasi Fina
Summary: This study investigates the switching speed and mechanisms in ferroelectric HfO2 films, revealing that films with a higher amount of monoclinic paraelectric phase exhibit faster switching speeds and can enable synaptic-like activity. Additionally, the polarization dynamics in pure orthorhombic ferroelectric phase films show a long characteristic time, suggesting the presence of non-archetypical switching mechanisms.
Article
Physics, Multidisciplinary
Sergey Belim, Ilya Tikhomirov
Summary: This article addresses the problem of modeling thin epitaxial iron films on a Cu (100) substrate by calculating the surface potential. The simulation aims to determine the film structure. It is found that the copper substrate stabilizes the fcc crystal lattice in the iron film at low temperatures, whereas bulk iron samples have a bcc crystal lattice. Furthermore, the interface effect causes additional vertical deformations in the first two layers of iron above the substrate.
Article
Chemistry, Physical
Da Hye Yang, Francesco Ricci, Fredrik L. Nordstrom, Na Li
Summary: Through systematic evaluation of the oiling-out behavior of procaine, we identified both stable and metastable liquid-liquid phase separation, and established phase diagrams to assist in rational selection of crystallization strategies.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Engineering, Biomedical
Kazuo Onuma, Mari M. Saito, Yasuo Yamakoshi, Mayumi Iijima, Yu Sogo, Koichi Momma
Summary: The transformation of soluble calcium phosphates to metastable octacalcium phosphate (OCP) in specific conditions provides a new approach for repairing teeth. The hybrid calcium phosphates produced by this transformation, consisting of HAP cores and highly reactive outer OCP layers, show promise for treating dentin caries.
ACTA BIOMATERIALIA
(2021)
Article
Materials Science, Multidisciplinary
Kazuma Kunimatsu, Tufan Roy, Jun Okabayashi, Tomoki Tsuchiya, Tomohiro Ichinose, Masahito Tsujikawa, Masafumi Shirai, Shigemi Mizukami
Summary: This study investigates the structure and magnetism of epitaxial thin films, finding that the bcc phase in Co1-xMnx alloys exhibits attractive properties for magnetics and spintronics.
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2022)
Article
Engineering, Electrical & Electronic
Anqi Zhang, Daheng Liu, Teng Yang, Song Ma, Zhidong Zhang
Summary: This study investigates the electrical and magnetoelectrical transport properties of FeTe2 films and reveals the effects of film thickness on magnetoresistance and magnetic phase transition. The variable range hopping conductive mechanism and magnetic transition suppression are also explained.
ACS APPLIED ELECTRONIC MATERIALS
(2022)
Article
Chemistry, Physical
Y. Hirayama, M. Shigeta, Z. Liu, N. Yodoshi, A. Hosokawa, K. Takagi
Summary: By controlling the cooling rate using the low-oxygen induction thermal plasma process, both stable and metastable phases of anisotropic Nd-Fe ultrafine particles can be selectively prepared, with narrow particle size distribution and good crystallinity. The alloy powders obtained exhibit anisotropy and can be aligned by external magnetic field, paving the way for a new-generation anisotropic permanent magnet.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Electrical & Electronic
Di Wang, Xiaochen Ma, Hongdi Xiao, Yong Le, Jin Ma
Summary: This study successfully prepared epitaxial beta-Ga2O3 films with different Ta doping concentrations, showcasing the ability to control carrier concentration and electrical properties by adjusting Ta concentration. The obtained films exhibited high quality single crystal structure and excellent transmittance in the visible light region.
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2021)
Article
Chemistry, Physical
Koushik Jagadish, Rajeev Kumar Rai, Mrityunjay Pandey, U. Chandni, N. Ravishankar
Summary: Electron microscopy studies have revealed exciting aspects of the structure and phase stability in the tin-oxygen system, clarifying unexplained features of the reported microstructures in the SnO system and providing new insights into the mutual stabilization of metastable phases in the oxides of Sn.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Physical
Yiming Shi, Junhua Meng, Jingren Chen, Yanmin Li, Rui Wu, Jinliang Wu, Zhigang Yin, Xingwang Zhang
Summary: Due to good lattice matching and bipolar doping behavior, wide bandgap SrTiO3 (STO) is considered a promising substrate for the heteroepitaxial growth of beta-Ga2O3 to construct (opto-)electronic devices. However, the growth of beta-Ga2O3 film on STO (111) substrate has not been studied extensively. In this work, beta-Ga2O3 (201) thin films were epitaxially grown on STO (111) substrates by low pressure chemical vapor deposition. The impact of source and growth temperatures on the crystal quality and surface roughness of the beta-Ga2O3 films was investigated. The results show that under optimized conditions, the heteroepitaxial beta-Ga2O3 film exhibited narrow X-ray diffraction rocking curve and low surface roughness. Epitaxial growth of beta-Ga2O3 films on STO substrates lays the foundation for future device applications.
APPLIED SURFACE SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Claudia Schnitter, Johanna Rosen, Hans Hogberg
Summary: Epitaxial growth of ZrB2 films on Si(100) substrates at 900 degrees C using direct-current magnetron sputter deposition from sintered ZrB2 targets is demonstrated. Two epitaxial relationships are determined from pole figure measurements, with a measure of epitaxial quality obtained from rocking curve measurements of the 100 and 102 peaks. The film composition is found to be ZrB2.3 and a previously unreported crystallographic relationship is identified.
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE
(2022)
Article
Nanoscience & Nanotechnology
K. Srimark, S. Dasari, A. Sharma, P. Wangyao, B. Gwalani, T. Rojhirunsakool, S. Gorsse, R. Banerjee
Summary: This study reveals that the alternating FCC and BCC lamellar microstructure in the Al0.7CoCrFeNi high entropy alloy is a result of non-equilibrium partitionless solidification followed by solid-state decomposition. Isothermal annealing further drives these individual sub-systems towards equilibrium via precipitation of ordered intermetallic phases. The transformation in FCC lamellae initiates by the formation of metastable L1(2) precipitates at shorter annealing times, which are eventually replaced by the equilibrium BCC and B2 phases.
SCRIPTA MATERIALIA
(2021)
Article
Chemistry, Physical
Rebecca Helmreich, Thomas Fauster
Summary: The molecular orbitals of MgTPP deposited on epitaxial MgO films on Ag (100) were investigated using ultraviolet photoelectron spectroscopy and two-photon photoemission. The energy levels of the electronic states were found to be pinned to the vacuum level, and the band gap was determined to be 3.88 +/- 0.07 eV, which was largely independent of the thickness of the MgO layer.
Article
Nanoscience & Nanotechnology
B. Rogez, S. Cao, G. Dujardin, G. Comtet, E. Le Moal, A. Mayne, E. Boer-Duchemin
Article
Chemistry, Physical
G. Dujardin, E. Boer-Duchemin, E. Le Moal, A. J. Mayne, D. Riedel
Article
Physics, Applied
Jean-Francois Bryche, Gregory Barbillon, Bernard Bartenlian, Gerald Dujardin, Elizabeth Boer-Duchemin, Eric Le Modul
JOURNAL OF APPLIED PHYSICS
(2018)
Article
Nanoscience & Nanotechnology
Shuiyan Cao, Eric Le Moal, Quanbo Jiang, Aurelien Drezet, Serge Huant, Jean-Paul Hugonin, Gerald Dujardin, Elizabeth Boer-Duchemin
BEILSTEIN JOURNAL OF NANOTECHNOLOGY
(2018)
Article
Physics, Multidisciplinary
Delphine Pommier, Remi Bretel, Luis E. Parra Lopez, Florentin Fabre, Andrew Mayne, Elizabeth Boer-Duchemin, Gerald Dujardin, Guillaume Schull, Stephane Berciaud, Eric Le Moal
PHYSICAL REVIEW LETTERS
(2019)
Article
Optics
Shuiyan Cao, Moustafa Achlan, Jean-Francois Bryche, Philippe Gogol, Gerald Dujardin, Georges Raseev, Eric Le Moal, Elizabeth Boer-Duchemin
Article
Nanoscience & Nanotechnology
Shuiyan Cao, Mario Zapata-Herrera, Alfredo Campos, Eric Le Moal, Sylvie Marguet, Gerald Dujardin, Mathieu Kociak, Javier Aizpurua, Andrey Borissov, Elizabeth Boer-Duchemin
Article
Chemistry, Multidisciplinary
Ricardo Javier Pena Roman, Remi Bretel, Delphine Pommier, Luis Enrique Parra Lopez, Etienne Lorchat, Elizabeth Boer-Duchemin, Gerald Dujardin, Andrei G. Borisov, Luiz Fernando Zagonel, Guillaume Schull, Stephane Berciaud, Eric Le Moal
Summary: This study demonstrates the local and electrical control of photoluminescence in monolayer WS2 using a nonplasmonic tip and tunneling current of a scanning tunneling microscope. The results show that short-range photoluminescence quenching is present due to near-field electromagnetic effects, independent of the bias voltage. Additionally, a bias-voltage-dependent long-range photoluminescence quenching is observed when the sample is positively biased.
Article
Physics, Multidisciplinary
Song Jiang, Tomas Neuman, Remi Bretel, Alex Boeglin, Fabrice Scheurer, Eric Le Moal, Guillaume Schull
Summary: A scanning tunneling microscope was used to investigate the fluorescence of a charged molecule (quinacridone) adsorbed on a metallic sample covered with sodium chloride. The fluorescence from both neutral and positively charged species was observed and analyzed using hyperresolved fluorescence microscopy. A many-body model was developed based on the analysis of voltage, current, and spatial dependences of fluorescence and electron transport features. This model reveals that the charge states of quinacridone can vary transiently or permanently depending on the voltage and substrate properties.
PHYSICAL REVIEW LETTERS
(2023)
Article
Materials Science, Multidisciplinary
Ricardo Javier Pena Roman, Delphine Pommier, Remi Bretel, Luis E. Parra Lopez, Etienne Lorchat, Julien Chaste, Abdelkarim Ouerghi, Severine Le Moal, Elizabeth Boer-Duchemin, Gerald Dujardin, Andrey G. Borisov, Luiz F. Zagonel, Guillaume Schull, Stephane Berciaud, Eric Le Moal
Summary: This study investigates the generation of excitons in monolayer WS2 using inelastic electron tunneling in a scanning tunneling microscope. Optical spectroscopy and Fourier-space optical microscopy reveal that the bias polarity of the tunnel junction determines the spectral and angular distribution of the emitted light.
Article
Chemistry, Physical
Niklas Humberg, Remi Bretel, Alexander Eslam, Eric Le Moal, Moritz Sokolowski
JOURNAL OF PHYSICAL CHEMISTRY C
(2020)
Article
Materials Science, Multidisciplinary
Ala Husseen, Severine Le Moal, Hamid Oughaddou, Gerald Dujardin, Andrew Mayne, Eric Le Moal
Article
Materials Science, Multidisciplinary
Shuiyan Cao, Eric Le Moal, Florian Bigourdan, Jean-Paul Hugonin, Jean-Jacques Greffet, Aurelien Drezet, Serge Huant, Gerald Dujardin, Elizabeth Boer-Duchemin
Proceedings Paper
Nanoscience & Nanotechnology
Shuiyan Cao, Mederic Lequeux, Eric Le Moal, Aurelien Drezet, Serge Huant, Gerald Dujardin, Elizabeth Boer-Duchemin
Article
Materials Science, Multidisciplinary
Eric Le Moal, Sylvie Marguet, Damien Canneson, Benoit Rogez, Elizabeth Boer-Duchemin, Gerald Dujardin, Tatiana V. Teperik, Dana-Codruta Marinica, Andrey G. Borisov