Theory of quantum paraelectrics and the metaelectric transition

We present a microscopic model of the quantum paraelectric-ferroelectric phase transition with a focus on the influence of coupled fluctuating phonon modes. These may drive the continuous phase-transition first order through a metaelectric transition and furthermore stimulate the emergence of a textured phase that preempts the transition. We discuss two further consequences of fluctuations, first for the heat capacity, and second we show that the inverse paraelectric susceptibility displays chi(-1)similar to T-2 quantum critical behavior, and can also adopt a characteristic minimum with temperature. Finally, we discuss the observable consequences of our results.