4.6 Article

Verwey transition in Fe3O4 at high pressure: Quantum critical point at the onset of metallization

Journal

PHYSICAL REVIEW B
Volume 78, Issue 10, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.78.100401

Keywords

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Funding

  1. Ministry of Science and Higher Education [1 P03B 001 29, 1 P03B 01 530]
  2. COST P-16 European Project

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We provide evidence for the existence of a quantum critical point at the metallization of magnetite Fe3O4 at pressure p(c)approximate to 8 GPa. We show that the present ac magnetic-susceptibility data support earlier resistivity data. The Verwey temperature scales with pressure T-V similar to(1-p/p(c))(nu) with nu similar to 1/3. The resistivity data show a temperature dependence rho(T)=rho(0)+AT(n) with n similar or equal to 3 above and 2.5 at the critical pressure, respectively. This difference in n with pressure is a sign of critical behavior at p(c). The magnetic susceptibility is smooth near p(c), both at the Verwey transition and near the lower temperature ferroelectric anomaly.

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