4.6 Article

Isotope shift of the electric-dipole transition in Os-

Journal

PHYSICAL REVIEW A
Volume 84, Issue 6, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.84.062510

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Funding

  1. German Research Foundation (DFG) [KE1369/1-1]
  2. European Research Council [StG 259209]
  3. MPIK

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The isotope shift of the bound-bound electric dipole transition at 1162.75 nm in the osmium anion was measured by high-precision collinear laser spectroscopy. The transition was observed in all naturally occurring isotopes, including Os-184(-) with a natural abundance of 0.02%. We combined the data with our prior measurements of the hyperfine structure in Os-187(-) and Os-189(-) and used them to determine experimental values for the isotope shift coefficients. The normal mass shift, specific mass shift, and field shift coefficients were found to be M-NMS = 141.4 GHz u, M-SMS = 2.4(12.6) THz u, and F = 16.2(9.9) GHz fm(-2), respectively. Theoretical values for the M-SMS and F parameters were calculated based on a series of relativistic configuration interaction computations and a Fermi-like charge distribution and found to be in good agreement with the experimental values.

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