4.6 Article

Singular Hylleraas three-electron integrals

Journal

PHYSICAL REVIEW A
Volume 77, Issue 3, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.77.032511

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Calculations of the leading quantum electrodynamics effects in few-electron systems involve singular matrix elements of interelectronic distances of the form 1/r(i)(3) and 1/r(ij)(3). Integrals that result when the nonrelativistic wave function is represented by a Hylleraas basis are studied. Recursion relations for various powers of the electron coordinates and the master integrals are derived in a form suited for high-precision numerical evaluations.

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