Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 16, Issue 19, Pages 8812-8818Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp54677b
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Funding
- Spanish Ministry of Education through a FPU fellowship
- JAE-DOC program ofCSIC
- Spanish MINECO [CTQ2008-02578, CTQ2012-37404-C02-01]
- Consolider SAUUL [CSD2007-00013]
- European Union [PITN-GA-2008-214962]
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The correlation between chemical structure and dynamics has been explored in a series of molecules with increasing structural complexity in order to investigate its influence on bond cleavage reaction times in a photodissociation event. Femtosecond time-resolved velocity map imaging spectroscopy reveals specificity of the ultrafast carbon-iodine (C-I) bond breakage for a series of linear (unbranched) and branched alkyl iodides, due to the interplay between the pure reaction coordinate and the rest of the degrees of freedom associated with the molecular structure details. Full-dimension time-resolved dynamics calculations support the experimental evidence and provide insight into the structure-dynamics relationship to understand structural control on time-resolved reactivity.
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