Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 14, Issue 37, Pages 12807-12817Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cp41214d
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Funding
- National Science Centre of Poland [N N202 126337]
- European Union through the Innovative Economy grant MIME [POIG.01.01.02-00-108/09]
- Deutsche Forschungsgemeinschaft
- DFG-cluster of excellence Munich Centre for Advanced Photonics''
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The photochemistry of the hydrogen-bonded oxotitanium porphyrin-water complex (TiOP-H2O) has been explored with electronic-structure calculations. It is shown that intramolecular charge-transfer processes, which are initiated by the excitation of the Soret band of TiOP, accumulate electronic charge on the oxygen atom of TiOP, which in turn abstracts a hydrogen atom from water by an exoenergetic and essentially barrierless hydrogen-transfer reaction, resulting in the TiPOH center dot-OH center dot biradical. About 75% of the absorbed photon energy is thus stored as chemical energy in two ground-state radicals. Absorption of a second photon by TiPOH center dot can result in the detachment of the H-center dot radical and recovery of the photocatalyzer TiOP. Again, about 75% of the photon energy is stored in the dissociation energy of TiPOH center dot. Overall, a water molecule is decomposed into H-center dot and OH center dot radicals by the absorption of two visible photons. Exoenergetic radical recombination reactions can yield molecular hydrogen, molecular oxygen or hydrogen peroxide as closed-shell products.
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