Article
Chemistry, Physical
I Cabria
Summary: This study calculated the hydrogen storage capacities of nanoporous carbons using simple theoretical methods that do not involve computationally expensive calculations. The results suggest that these methods are useful for designing novel materials for hydrogen storage.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Polymer Science
Christophe Daniel, Paola Rizzo, Baku Nagendra, Antonietta Cozzolino, Gaetano Guerra
Summary: NC PPO films show higher guest uptake and diffusivity compared to other types of films, particularly with the orientation of their NC phases being perpendicular to the film plane. These properties make NC PPO films potentially useful for applications such as organic pollutant control, molecular separations, and molecular sensors.
Article
Computer Science, Artificial Intelligence
Zhenpeng Yao, Benjamin Sanchez-Lengeling, N. Scott Bobbitt, Benjamin J. Bucior, Sai Govind Hari Kumar, Sean P. Collins, Thomas Burns, Tom K. Woo, Omar K. Farha, Randall Q. Snurr, Alan Aspuru-Guzik
Summary: Reticular frameworks are crystalline porous materials that have desirable properties for various applications, but the diversity of building blocks presents challenges for materials design. An automated nanoporous materials discovery platform powered by a supramolecular variational autoencoder is proposed for generative design of reticular materials, showing high fidelity in capturing structural features and promising optimization capability for gas separation.
NATURE MACHINE INTELLIGENCE
(2021)
Article
Chemistry, Physical
Zhihao Yang, Xiaoqing Du, Xiaoqiu Ye, Xiaodong Qu, Huiling Duan, Yufeng Xing, Li-Hua Shao, Changan Chen
Summary: The study presents the hydrogen isotope storage properties of free-standing monolithic nanoporous palladium (NP-Pd) with different microstructure feature sizes, showing high hydrogen separation efficiency and reversible storage capacity.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Luhui Han, Huogen Huang, Pengguo Zhang, Ce Ma, Xuefeng Wang, Ge Sang, Wenhua Luo
Summary: The study found that crystalline Zr2Co alloy shows higher feasibility in tritium treatment, demonstrating lower equilibrium pressure and better ability to suppress disproportionation reactions.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Materials Science, Multidisciplinary
L. J. Huang, H. Wang, L. Z. Ouyang, M. Zhu, H. J. Lin
Summary: This study solves the problem of sluggish de/hydrogenation kinetics of Mg-based amorphous alloys by building a hydrogen pump on the surface of the alloys. The hydrogen pump effect of seeded crystalline alloy is confirmed, greatly enhancing the hydrogen absorption rate and low-temperature dehydrogenation kinetics.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2024)
Article
Polymer Science
Baku Nagendra, Paola Rizzo, Christophe Daniel, Gaetano Guerra
Summary: The transparency of polymer films is influenced by the planar orientations of nanoporous-crystalline (NC) phases of sPS and PPO, with sPS and PPO exhibiting opposite behaviors. Improvements in transparency are observed when the chain axes of the NC phases are oriented parallel or perpendicular to the film plane for sPS and PPO, respectively.
Article
Chemistry, Physical
Shengli Zhu, Yiyang Zhou, Yanqin Liang, Zhaoyang Li, Shuilin Wu, Zhenduo Cui, Shuiyuan Luo
Summary: In this study, a self-standing nanoporous NiAlTi/Al3Ti hybrid catalyst was prepared and demonstrated outstanding performance for the hydrogen evolution reaction. The amorphous NiAlTi acted as the active phase, while the conductive Al3Ti support provided an effective electron pathway, resulting in a small overpotential and good stability in alkaline media. This work offers a feasible strategy for exploring efficient and low-cost electrocatalysts for energy conversion applications.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Miriam Marques, Miriam Pena-Alvarez, Miguel Martinez-Canales, Graeme J. Ackland
Summary: We demonstrate that hydrogen in metal superhydride compounds can exist in two distinct states-atomic and molecular. At low pressures, additional hydrogen atoms form molecules with electronic states below the Fermi energy, resulting in low-symmetry structures with large unit cells. At high pressures, molecules become unstable and all hydrogens become atomic. This study uses density functional theory to compare BaH4 with other stoichiometries and cations, and shows that increased temperature and zero-point motion favor high-symmetry atomic states, with bond rearrangements occurring on a picosecond time scale.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Review
Chemistry, Physical
Ahmed M. Elberry, Jagruti Thakur, Annukka Santasalo-Aarnio, Martti Larmi
Summary: Analyzing the status and potential of compressed hydrogen storage technologies requires a techno-economic chain analysis to evaluate their feasibility; while some technologies are immature, they still show promise for development, highlighting the important role of hydrogen in balancing renewable electricity production.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Engineering, Environmental
Nikolaos Kostoglou, Christian Koczwara, Sebastian Stock, Christos Tampaxis, Georgia Charalambopoulou, Theodore Steriotis, Oskar Paris, Claus Rebholz, Christian Mitterer
Summary: The study investigates the potential applications of a nanoporous polymer-/polyaniline-derived activated carbon (PDAC) in hydrogen storage and supercapacitor energy storage. The PDAC demonstrates superior hydrogen adsorption performance and supercapacitor cell performance compared to conventional commercial activated carbon, attributed to the smaller pore sizes of the PDAC structure.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Polymer Science
Vipin G. Krishnan, Angel Mary Joseph, Surendran Kuzhichalil Peethambharan, E. Bhoje Gowd
Summary: Hierarchically porous crystalline nanoporous aerogels of syndiotactic polystyrene (sPS) with two nanoporous crystalline forms were prepared and showed promising dielectric, thermal, and acoustic properties. The aerogels also exhibited excellent oleophilicity, making them suitable for oil/organic solvent separation experiments.
Article
Chemistry, Physical
Shixun Bai, Mohammad Piri
Summary: Hydrogen as a clean substitute for fossil fuels has attracted significant interest. This study explores the potential and limitations of nanoporous materials for mobile H2 storage and identifies key factors influencing H2 storage capacity, such as pore size and fluid-wall interaction. The results demonstrate that decreasing pore sizes can increase the confined density of H2, but it is subject to energy requirements. Furthermore, the disproportionality in density change in adsorption layers leads to a decay in confinement benefits with increasing pressure.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Engineering, Environmental
Ki Hun Park, Dong Hyun Kim, Minjun Cha
Summary: A new structure II (sII) hydrate former, cyclobutanemethanol (CBM), was discovered for potential gas storage applications. The binary (CBM + CH4) hydrate showed higher thermodynamic stability and superior CH4 storage capacity compared to other hydrates, indicating potential for gas storage applications.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Lucyna Firlej, Bogdan Kuchta, Katarzyna Walczak, Catherine Journet
Summary: Nanoporous carbons are considered as promising candidates for hydrogen storage by physisorption, but their storage limitations and ways to improve performance are discussed. The focus is on surface area and adsorption energy as key parameters, with suggestions for modifications to the carbon nanostructure. The positive effects of carbon substitutions by B and Be atoms are described, with preliminary results showing potential for improved hydrogen adsorption energy.
Article
Polymer Science
Baku Nagendra, Paola Rizzo, Christophe Daniel, Gaetano Guerra
Summary: The transparency of polymer films is influenced by the planar orientations of nanoporous-crystalline (NC) phases of sPS and PPO, with sPS and PPO exhibiting opposite behaviors. Improvements in transparency are observed when the chain axes of the NC phases are oriented parallel or perpendicular to the film plane for sPS and PPO, respectively.
Article
Polymer Science
Christophe Daniel, Paola Rizzo, Baku Nagendra, Antonietta Cozzolino, Gaetano Guerra
Summary: NC PPO films show higher guest uptake and diffusivity compared to other types of films, particularly with the orientation of their NC phases being perpendicular to the film plane. These properties make NC PPO films potentially useful for applications such as organic pollutant control, molecular separations, and molecular sensors.
Article
Polymer Science
Antonietta Cozzolino, Baku Nagendra, Paola Rizzo, Christophe Daniel, Gaetano Guerra
Summary: The ability of poly(2,6-dimethyl-1,4-phenylene)oxide (PPO) films to absorb organic pollutants dissolved in water is shown. The crystalline structure and orientation on the film surface play a significant role in determining the absorption efficiency.
EUROPEAN POLYMER JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Jenny G. Vitillo, Christopher J. Cramer, Laura Gagliardi
Summary: Highly correlated systems, especially those containing transition metals, are common in catalysis. Existing single determinantal methods using Kohn Sham density functional theory often fail to accurately account for the significant static correlation in such systems. Although more rigorous multiconfigurational methods have been applied in some specific cases, their use in catalysis remains limited. This paper discusses the obstacles hindering the routine application of multireference wave function theoretical calculations to catalytic systems and the current progress in overcoming these obstacles.
ISRAEL JOURNAL OF CHEMISTRY
(2022)
Article
Polymer Science
Baku Nagendra, Antonietta Cozzolino, Christophe Daniel, Paola Rizzo, Gaetano Guerra
Summary: This study presents nano-porous-crystalline polymer films with a high surface area and fast organic pollutant uptakes, based on a commercially available thermoplastic polymer. These films exhibit much higher diffusivities for organic pollutant sorption and desorption compared to other high-diffusivity polymer films. These new high-SA polymer films are expected to find many applications due to their extremely fast kinetics of pollutant uptakes and high thermal and mechanical stability.
Article
Polymer Science
Baku Nagendra, Christophe Daniel, Paola Rizzo, Gaetano Guerra
Summary: Four different preparation methods for nanoporous-crystalline films of PPO with high crystallinity and high c-perpendicular orientation, even for thickness as low as 5 μm, are described in this paper. The results support the hypothesis that the c-perpendicular orientation is due to the formation of flat-on crystalline lamellae through nanoconfined co-crystallization of PPO. An anomalous temperature dependence of c-perpendicular orientation for limonene-induced co-crystallization with PPO is also explained.
POLYMERS FOR ADVANCED TECHNOLOGIES
(2022)
Article
Multidisciplinary Sciences
Jenny G. Vitillo, Matthew D. Eisaman, Edda S. P. Aradottir, Fabrizio Passarini, Tao Wang, Stafford W. Sheehan
Summary: According to the 2021 IPCC report, CO2 removal measures are necessary to achieve climate goals. The strategy to mitigate emissions should focus on sources that require the least energy and capital investment per ton of CO2, while favoring processes that yield high-value products.
Article
Energy & Fuels
Rashmi Dahal, Jenny G. Vitillo, Anna C. Asland, Christoph Frommen, Stefano Deledda, Olena Zavorotynska
Summary: Magnesium borohydride (Mg(BH4)(2)) is a solid-state hydrogen storage compound that has high hydrogen densities and low operational temperature. This study used spectroscopic methods to investigate the reaction intermediates and provided additional insights into this decomposition reaction.
Article
Polymer Science
Finizia Auriemma, Christophe Daniel, Manohar Golla, Baku Nagendra, Paola Rizzo, Oreste Tarallo, Gaetano Guerra
Summary: This review focuses on relevant information about PPO crystallization, with a particular emphasis on nanoporous crystalline and co-crystalline forms. It discusses preparation methods, structures, properties, and applications of NC and CC samples, with a particular emphasis on the impressive solubility and diffusivity of organic guests in NC PPO samples. The study mainly examines films, especially axially oriented NC films, revealing their structural features and future research prospects.
Article
Polymer Science
Antonietta Cozzolino, Simone Pappalardo, Paola Rizzo, Gaetano Guerra
Summary: This study reports the sorption behavior of different crystalline forms of syndiotactic polystyrene (sPS) films towards long aliphatic carboxylic acids and dicarboxylic acids. The results show that the epsilon-form sPS film can selectively and rapidly adsorb these acids, while the delta-form sPS film can only sorb them from the amorphous phase.
Article
Chemistry, Multidisciplinary
Aida Kiani, M. Rosaria Acocella, Veronica Granata, Elisabetta Mazzotta, Cosimino Malitesta, Gaetano Guerra
Summary: This paper presents a sustainable and green method for producing highly oxidized carbon black using dry ball milling. The mechanical energy generated by colliding milling balls easily breaks and builds chemical bonds, resulting in new oxygenated functional groups. The method is environmentally friendly, requiring no solvents or additional reagents.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2022)
Article
Biochemistry & Molecular Biology
Angelo Maspero, Federico Vavassori, Luca Nardo, Guglielmo Vesco, Jenny G. Vitillo, Andrea Penoni
Summary: We have developed a simple and efficient strategy to enhance the fluorescence of biocompatible biindole diketonates (bdks) in the visible spectrum through difluoroboronation. The fluorescence quantum yield is significantly increased, independent of indole substitutions, by stabilizing the excited state and reducing non-radiative decay rates. This stabilization enables significant O-1(2) photosensitized production.
Article
Materials Science, Multidisciplinary
Baku Nagendra, Syed Salman, Hans Peter Bloch, Christophe Daniel, Paola Rizzo, Rosalba Fittipaldi, Gaetano Guerra
Summary: The study investigates the properties of sulfonated poly(phenylene oxide) (PPO) films with both hydrophilic amorphous phase and hydrophobic crystalline phase, achieved through solid-state film sulfonation. The semicrystalline-sulfonated PPO (SPPO) films exhibit superior hydrothermal and solvent stability compared to amorphous SPPO films. Moreover, the semicrystalline SPPO films demonstrate faster guest sorption kinetics due to the nanoporous-crystalline (NC) morphology.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Baku Nagendra, Antonietta Cozzolino, Maria Rosaria Acocella, Christophe Daniel, Paola Rizzo, Gaetano Guerra
Summary: Films of nanoporous-crystalline poly(2,6-dimethyl-1,4-phenylene) oxide (PPO) can absorb apolar organic guest molecules effectively and also polar molecules from concentrated organic solutions. When obtained by spontaneous oxidation of benzyl alcohol (BAL) in aqueous solution, benzyl alcohol and benzoic acid (BA) in a 1/1 hydrogen-bonded dimer can be greatly absorbed by the NC PPO films, which is unprecedented for absorbent materials. This ability to absorb the BAL/BA dimer can be utilized in water purification.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Materials Science, Multidisciplinary
Baku Nagendra, Syed Salman, Christophe Daniel, Paola Rizzo, Gaetano Guerra
Summary: This study explores the influence of guest and processing conditions on the high surface area nanoporous-crystalline PPO films. The researchers found suitable preparation procedures that lead to high transparency and toughness, making them suitable for organic pollution remediation, molecular separations, and molecular sensing.
MATERIALS ADVANCES
(2023)
Article
Chemistry, Physical
Sergey Yu. Ketkov, Sheng-Yuan Tzeng, Elena A. Rychagova, Anton N. Lukoyanov, Wen-Bih Tzeng
Summary: Metallocenes, including methylcobaltocene, play important roles in various fields of chemistry. The ionization energy and vibrational structure of (Cp ')(Cp)Co can be influenced by introducing methyl substituents. The mass-analyzed threshold ionization spectrum and DFT calculations provide accurate information about the properties and transformations of (Cp ')(Cp)Co.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Review
Chemistry, Physical
Qifeng Mu, Jian Hu
Summary: Polymer mechanochemistry has experienced a renaissance due to the rapid development of mechanophores and principles governing mechanochemical transduction or material strengthening. It has not only provided fundamental guidelines for converting mechanical energy into chemical output, but also found applications in engineering and smart devices.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Da Hye Yang, Francesco Ricci, Fredrik L. Nordstrom, Na Li
Summary: Through systematic evaluation of the oiling-out behavior of procaine, we identified both stable and metastable liquid-liquid phase separation, and established phase diagrams to assist in rational selection of crystallization strategies.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Vikki Anand Varma, Simmie Jaglan, Mohd Yasir Khan, Sujin B. Babu
Summary: Designing engineering structures like nanocages, shells, and containers through self-assembly of colloids is a challenging problem. This work proposes a simple model for the subunit, which leads to the formation of monodispersed spherical cages or containers. The model with only one control parameter can be used to design cages with the desired radius.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Hainan Jiang, Yaolong He, Xiaolin Li, Zhiyao Jin, Huijie Yu, Dawei Li
Summary: The cycling lifespan and coulombic efficiency of lithium-ion batteries are crucial for high C-rate applications. The Li-ion concentration plays a crucial role in determining the mechanical integrity and structural stability of electrodes. This study focuses on graphite as the working electrode and establishes an experimental system to investigate the mechanical properties of composite graphite electrode at different C-rates. Considering the effect of Li-ion concentration in stress analysis is found to be significant.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Zhiye Wang, Yunchuan Li, Mingjun Sun
Summary: This study investigates the influence of intramolecular pi-pi interactions on the electronic transport capabilities of molecules. By designing and analyzing three pi-conjugated molecules, the researchers observe that different pi-conjugated structures have varying effects on electron transport. The findings provide a theoretical foundation for designing single-molecule electronic devices with multiple electron channels based on intramolecular pi-pi interactions.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Yuandong Xu, Haoyang Feng, Chaoyang Dong, Yuqing Yang, Meng Zhou, Yajun Wei, Hui Guo, Yaqing Wei, Jishan Su, Yingying Ben, Xia Zhang
Summary: Hollow MoS2 cubes and spheres were successfully synthesized using a one-step hydrothermal method with the hard template method. The hollow MoS2 cubes exhibited higher specific capacitance and energy density compared to the hollow MoS2 spheres. The symmetrical supercapacitors assembled with these hollow structures showed good performance and high capacity retention after multiple cycles. These findings suggest that controlling the pore structure and surface characteristics of MoS2 is crucial for enhancing its electrochemical properties.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Ainhoa Oliden-Sanchez, Rebeca Sola-Llano, Joaquin Perez-Pariente, Luis Gomez-Hortiguela, Virginia Martinez-Martinez
Summary: The combination of photoactive molecules and inorganic structures is important for the development of advanced materials in optics. In this study, bulky dyes were successfully encapsulated in a zeolitic framework, resulting in emission throughout the visible spectrum.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Miaomiao Zhang, Cunyuan Pei, Qiqi Xiang, Lintao Liu, Zhongxu Dai, Huijuan Ma, Shibing Ni
Summary: The design of a solid electrolyte interphase (SEI) plays a crucial role in improving the electrochemical performance of anode materials. In this study, lithium difluoro(oxalate)borate (LiDFOB) is used as an electrolyte additive to form a protective SEI film on Li3VO4 (LVO) anodes. The addition of LiDFOB results in a dense, uniform, stable, and LiF-richer SEI, which enhances the Li-ion storage kinetics. The generated SEI also prevents further decomposition of the electrolyte and maintains the morphology of LVO anodes during charge/discharge processes. This work demonstrates the effectiveness of LiDFOB as a multi-functional additive for LiPF6 electrolytes and provides insights into SEI construction for high-performance LVO anodes.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
B. V. Andryushechkin, T. V. Pavlova, V. M. Shevlyuga
Summary: The atomic structure of the Ag(111)-p(4 x 4)-O phase was reexamined and two phases with the same periodicity were discovered. It was demonstrated that the accepted Ag6 model is incompatible with high-resolution oxygen-sensitive STM images.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
S. L. Romo-Avila, D. Marquez-Ruiz, R. A. Guirado-Lopez
Summary: In this study, we used density functional theory (DFT) calculations to investigate the interaction between model graphene oxide (GO) nanostructures and chlorine monoxide ClO. We aimed to understand the role of this highly oxidizing species in breaking C-C bonds and forming significant holes on GO sheets. Our results showed that C-C bonds in a single graphene oxide sheet can be broken through a simple mechanism involving the dissociation of two chemically attached ClO molecules. The formation of carbonyl groups and holes on the GO surface was also observed. This study provides important insights into the degradation of carbon nanotubes and the stability of GO during the myeloperoxidase (MPO) catalytic cycle.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Alberto Garcia-Fernandez, Birgit Kammlander, Stefania Riva, Hakan Rensmo, Ute B. Cappel
Summary: In this study, the X-ray stability of five different lead halide perovskite compositions (MAPbI3, MAPbCl3, MAPbBr3, FAPbBr3, CsPbBr3) was investigated using photoelectron spectroscopy. Different degradation mechanisms and resistance to X-ray were observed depending on the crystal composition. Overall, perovskite compositions based on the MA+ cation were found to be less stable than those based on FA+ or Cs+. Metallic lead formation was most easily observed in the chloride perovskite, followed by bromide, and very little in MAPbI3. Multiple degradation processes were identified for the bromide compositions, including ion migration, formation of volatile and solid products, as well as metallic lead. CsBr was formed as a solid degradation product on the surface of CsPbBr3.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Timofei Rostilov, Vadim Ziborov, Alexander Dolgoborodov, Mikhail Kuskov
Summary: The shock-loading behavior of nanomaterials is investigated in this study. It is found that shock compaction waves exhibit a distinct two-step structure, with the formation of faster precursor waves that travel ahead of the main compaction waves. The complexity of the shock Hugoniot curve of the tested nanomaterial is described, and the effect of initial porosity on the compressed states is demonstrated.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Sergey S. Nikitin, Alexander D. Koryakov, Elizaveta A. Antipinskaya, Alexey A. Markov, Mikhail V. Patrakeev
Summary: The stability of La1/3Sr2/3Fe1-xMnxO3-delta, a perovskite-type oxide, under reducing conditions is dependent on the manganese content. Increasing the manganese content leads to a decrease in stability. The behavior of iron and manganese in the oxide shows distinct differences, which can be attributed to the difference in the enthalpy of oxidation reactions. Additionally, the change in the La/Sr ratio affects the concentration of iron and manganese ions.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Mosayeb Naseri, Shirin Amirian, Mehrdad Faraji, Mohammad Abdur Rashid, Maicon Pierre Lourenco, Venkataraman Thangadurai, D. R. Salahub
Summary: Inspired by the successful transfer of freestanding ultrathin films of SrTiO3 and BiFeO3, this study assessed the structural stability and investigated the electronic, optical, and thermoelectric properties of a group of two-dimensional perovskite-type materials called perovskenes. The findings revealed that these materials are wide bandgap semiconductors with potential application in UV shielding. Moreover, they exhibit better electrical and thermal conductivity at high temperatures, enabling efficient power generation in thermoelectric devices.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
