Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 12, Issue 13, Pages 3108-3111Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c000271b
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Funding
- National Nature Science Foundation of China [50701040, 50631020]
- Ministry of Science and Technology of China [2009AA05Z106, 2010CB631304]
- Specialized Research Fund for the Doctoral Program of Higher Education of China [20070335005]
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The reaction details of hydrogen storage process of a ternary imide Li2Mg2N3H3 are elucidated for the first time. It is found that 1 mole of Li2Mg2N3H3 converts to a mixture of Mg(NH2)(2)-2LiH-MgNH on taking up 2 moles of H-2, and that the presence of MgNH in the Mg(NH2)(2)-2LiH system not only alters the dehydrogenation thermodynamics but also improves the dehydrogenation kinetics.
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