Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 10, Issue 32, Pages 4981-4986Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b810309g
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The average molecular orientation in the adsorbed water layers formed on amorphous SiO2 in ambient conditions was determined as a function of relative humidity using polarization attenuated total reflectance infrared spectroscopy (ATR-IR). The silicon oxide surface was prepared by chemically cleaning in aqueous solution, washing with water, and drying with argon. After drying, this produced a SiO2 surface with hydroxyl groups, giving rise to a water contact angle <5 degrees. Primarily two types of vibrational peaks that correspond to liquid water and solid-like water were observed in the adsorbed water layers formed on this surface at room temperature. The average orientation of the water molecules was determined from the dichroic ratio of s- to p-polarization absorbances. At low relative humidities, the highly hydrogen bonded solid-like structure exhibits a dichroic ratio as low as similar to 0.4, while the liquid water structure exhibits a dichroic ratio close to similar to 1.0. As the relative humidity increases, the dichroic ratio of both water structures approaches a dichroic ratio of 0.7 similar to 0.8, which is consistent with the random orientation of molecules of bulk water and ice.
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