4.4 Editorial Material

Low-thermal-conductivity group 13 chalcogenides as high-efficiency thermoelectric materials

Journal

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/pssa.201228680

Keywords

group 13 elements; thermal conductivity; thermoelectric; telluride

Ask authors/readers for more resources

Thermoelectric (TE) generators can directly generate electrical power from waste heat and are promising for use in power supplies and for realizing sustainable energy management. However, the low efficiencies of TE materials in converting heat to electricity is the main impediment to applying TE generators in many industries including exhaust heat recovery in automobiles. The efficiency of TE materials is quantified by a dimensionless figure of merit ZT. To enhance ZT, it is important to reduce the lattice thermal conductivity (?lat) of a material while maintaining a high electrical conductivity. Here, we review the TE properties of thallium-based compounds, mainly tellurides. Many thallium tellurides exhibit extremely low ?lat below 0.5?W?m-1?K-1, which is almost one third that of Bi2Te3 used in current TE devices. Of the thallium tellurides, Ag9TlTe5 has the highest ZT value of 1.2, which is higher than typical ZT values 0.8 of Bi2Te3; this is primarily due to the extremely low ?lat of Ag9TlTe5. In addition, we briefly review the TE properties of tellurides of other group 13 elements that contain structural vacancies such as Ga2Te3. Tellurides exhibit various vacancy distributions and hence have interesting TE properties. Based on the results of the TE properties of these tellurides, we propose a strategy for improving TE materials.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.4
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Multidisciplinary Sciences

Synthesis, microstructure, multifunctional properties of mayenite Ca12Al14O33 (C12A7) cement and graphene oxide (GO) composites

Chaval Sriwong, Chaiwat Phrompet, Wattana Tuichai, Attaphol Karaphun, Ken Kurosaki, Chesta Ruttanapun

SCIENTIFIC REPORTS (2020)

Article Materials Science, Multidisciplinary

Enhancement of Thermoelectric Figure of Merit of p-Type Nb0.9Ti0.1FeSb Half-Heusler Compound by Nanostructuring

Wanthana Silpawilawan, Sora-at Tanuslip, Yuji Ohishi, Hiroaki Muta, Ken Kurosaki

PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE (2020)

Correction Materials Science, Multidisciplinary

Thermal and mechanical properties of (U,Er)O2 (vol 389, pg 115, 2009)

Shinsuke Yamanaka, Ken Kurosaki, Masahito Katayama, Jun Adachi, Masayoshi Uno, Takeshi Kuroishi, Masatoshi Yamasaki

JOURNAL OF NUCLEAR MATERIALS (2021)

Article Physics, Applied

Controlled thermal expansion and thermoelectric properties of Mg2Si/Si composites

Jiahui Fu, Sora-at Tanusilp, Masaya Kumagai, Yuji Ohishi, Ken Kurosaki

Summary: The performance of a thermoelectric module is evaluated by the dimensionless figure of merit zT, while the thermal expansion of materials is also a crucial consideration. A large difference in thermal expansion rates between n- and p-type materials can result in device failures and performance reduction over time, highlighting the importance of both zT and material compatibility for practical applications.

JOURNAL OF APPLIED PHYSICS (2021)

Article Physics, Applied

A simple method for fabricating flexible thermoelectric nanocomposites based on bacterial cellulose nanofiber and Ag2Se

Dulyawich Palaporn, Wiyada Mongkolthanaruk, Sora-at Tanusilp, Ken Kurosaki, Supree Pinitsoontorn

Summary: This study fabricated flexible thermoelectric nanocomposites from bacterial cellulose and Ag2Se via a simple and inexpensive method, and demonstrated their excellent thermoelectric performance through experimental results. Moreover, the material exhibited high flexibility and scalability, making it suitable for industrial applications of modern flexible thermoelectric devices.

APPLIED PHYSICS LETTERS (2022)

Article Materials Science, Multidisciplinary

Large Anharmonicity and Low Lattice Thermal Conductivity of Thermoelectric Sn(SbTe2)2

Sora-at Tanusilp, Masaya Kumagai, Yuji Ohishi, Naoki Sadayori, Ken Kurosaki

Summary: The study shows that Sn(SbTe2)(2) has a large anharmonicity, leading to its low thermal conductivity, making it an excellent thermoelectric material with relatively high thermoelectric figure of merit.

PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS (2022)

Article Chemistry, Physical

The influence of Gd2O3 on shielding, thermal and luminescence properties of WO3-Gd2O3-B2O3 glass for radiation shielding and detection material

E. Kaewnuam, N. Wantana, S. Tanusilp, K. Kurosaki, P. Limkitjaroenporn, J. Kaewkhao

Summary: This study investigated the physical, structural, optical, shielding, thermal, and luminescent properties of WO3-Gd2O3-B2O3 glasses, with a focus on the impact of replacing WO3 with Gd2O3. The density of the glasses increased with higher concentrations of Gd2O3, while the optical absorption spectra showed absorbance in the ultraviolet and visible light regions. Despite a small degradation in shielding properties with increasing Gd2O3 content, the glass displayed strong photoluminescence and radioluminescence, making it a promising material for gamma-ray shielding and X-ray radiation detection applications at different temperatures.

RADIATION PHYSICS AND CHEMISTRY (2022)

Article Chemistry, Physical

Flexible Thermoelectric Paper and Its Thermoelectric Generator from Bacterial Cellulose/Ag2Se Nanocomposites

Dulyawich Palaporn, Wiyada Mongkolthanaruk, Kajornsak Faungnawakij, Ken Kurosaki, Supree Pinitsoontorn

Summary: A flexible thermoelectric paper was successfully fabricated using bacterial cellulose/silver selenide nanocomposites. The in situ synthesis of silver selenide particles within the bacterial cellulose structure resulted in a homogeneous distribution of submicrosize particles, leading to enhanced thermoelectric properties. The hot-pressing process further improved the microstructure and increased the power factor of the paper.

ACS APPLIED ENERGY MATERIALS (2022)

Article Chemistry, Physical

Enhancement of Thermoelectric Properties of n-Type Bi2Te3-xSex by Energy Filtering Effect

Yuhei Kawajiri, Sora-at Tanusilp, Masaya Kumagai, Manabu Ishimaru, Yuji Ohishi, Junya Tanaka, Ken Kurosaki

Summary: By introducing gold (Au) into n-type Bi2Te3-xSex, the researchers successfully enhanced the thermoelectric properties, achieving a significant increase in zT value at room temperature and a 75% improvement, making it a promising candidate for assembling high-efficiency thermoelectric modules.

ACS APPLIED ENERGY MATERIALS (2021)

Article Materials Science, Multidisciplinary

Ultralow Thermal Conductivity of Highly Dense ZrW2O8 Ceramics with Negative Thermal Expansion

Sora-at Tanusilp, Masaya Kumagai, Yuji Ohishi, Hideki Furusawa, Motoomi Suwabe, Ken Kurosaki

Summary: In this study, a highly dense bulk sample of ZrW2O8 was synthesized using spark plasma sintering technique, and its thermal conductivity, mechanical properties, and other physical properties were investigated. It was found that ZrW2O8 exhibited unique thermal properties and could be potentially used in thermal management areas.

ADVANCED ENGINEERING MATERIALS (2022)

Article Physics, Applied

Large thermopower in novel thermoelectric Yb(Si1-xGex)2 induced by valence fluctuation

Akinori Nishide, Sora-at Tanusilp, Wataru Kowa, Mitsuharu Yashima, Akira Nambu, Jun Hayakawa, Yuji Ohishi, Hiroaki Muta, Hidekazu Mukuda, Ken Kurosaki

Summary: The research demonstrates that by controlling the valence fluctuation, ytterbium silicide-based thermoelectric materials can achieve a high Seebeck coefficient and extremely low resistivity. This makes it possible to harvest energy from a cold source.

JOURNAL OF APPLIED PHYSICS (2022)

Article Nuclear Science & Technology

Phase behavior of oxidized Ce and Gd-doped (U,Zr)O2

Yifan Sun, Shiho Watanabe, Hiroaki Muta, Yuji Ohishi, Ken Kurosaki

Summary: Re-criticality analysis is crucial for safe retrieval and storage of the fuel debris at the Fukushima Dai-ichi Nuclear Power Plant. This study investigates the oxidation behavior and phase formation of Pu-doped and Gd-doped (U,Zr)O-2 solid solutions. Surrogate materials (CeO2) were used to mimic the behavior of PuO2. Analysis reveals the distribution and transformation of phases after oxidation.

JOURNAL OF NUCLEAR SCIENCE AND TECHNOLOGY (2023)

Review Physics, Applied

Rare-earth silicides: the promising candidates for thermoelectric applications at near room temperature

Sora-at Tanusilp, Ken Kurosaki

Summary: Metal silicides, including the well-known Mg2Si, are promising candidates for thermoelectric applications due to their low toxicity and high stability. Rare-earth (RE) silicides, with their special behaviors of heavy fermion or mixed valence, exhibit unusually large Seebeck coefficient and thermoelectric power factor at low temperatures, making them potential advantages for low-temperature thermoelectric applications.

JAPANESE JOURNAL OF APPLIED PHYSICS (2023)

Article Nuclear Science & Technology

Thermophysical and mechanical properties of LaB6 and CeB6 synthesized through spark plasma sintering

Yifan Sun, Yuji Ohishi, Junya Higaki, Hiroaki Muta, Ken Kurosaki

Summary: Following the Fukushima Daiichi nuclear power plant accident, the development of accident tolerant fuels (ATFs) has become important in promoting nuclear safety. This study investigates the properties of non-radioactive LaB6 and CeB6 to estimate the potential properties of UB6, a promising ATF with little known information. The comparison with UO2, UB2, and UB4 helps determine whether the fabrication of UB6 under high pressure or with other dopants is worthwhile for ATF development.

JOURNAL OF NUCLEAR SCIENCE AND TECHNOLOGY (2023)

No Data Available