4.5 Article

Synthesis and characterization of polyvinyl alcohol based multiwalled carbon nanotube nanocomposites

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ELSEVIER
DOI: 10.1016/j.physe.2014.03.026

Keywords

Carbon nanotube; Nanocomposite; Polymer-matrix composite; Grafting to; Scanning/Transmission Electron Microscopy; Thermogravimetric analysis

Funding

  1. EC FP7 program NAPEP [266600]
  2. Hungarian Scientific Research Foundation OTKA [NN 110676]
  3. European Union [TAMOP-4.2.2.A-11/1/KONV-2012-0047]
  4. European Social Fund [TAMOP-4.2.2.A-11/1/KONV-2012-0060]

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Multiwalled carbon nanotubes were synthesized by chemical vapor deposition over an Fe-Co/alumina catalyst. Nanotubes were then oxidized and grafted with polyvinyl alcohol (PVA). The obtained nanostructure was characterized by Raman spectroscopy, XRD, FTIR, EDX, SEM, TEM and TGA methods. FUR confirmed the presence of the characteristic peaks of the anticipated ester group. The formation of polymer nanocomposites based on polyvinyl alcohol and multiwalled carbon nanotubes was confirmed by SEM and TEM. High resolution electron micrographs revealed that the primary binding sites for [VA grafting are the sidewall defects of the nanotubes. The novelty of this work is the use of the Fischer esterification reaction for creating the permanent link between the nanotubes and the PVA matrix. (C) 2014 Elsevier B.V. All rights reserved.

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