4.5 Article

Size-induced changes of structural, magnetic and magnetocaloric properties of La0.7Ca0.2Ba0.1MnO3

Journal

PHYSICA B-CONDENSED MATTER
Volume 405, Issue 12, Pages 2733-2741

Publisher

ELSEVIER
DOI: 10.1016/j.physb.2010.03.059

Keywords

Particle size; Magnetocaloric effect; Nanoparticle

Funding

  1. National Key Basic Research [2007CB925002]
  2. National Nature Science Foundation of China [10804111, 10774146, 50672099, 50701042]
  3. Chinese Academy of Sciences

Ask authors/readers for more resources

The particle size effects on the structural, magnetic and magnetocaloric properties of La0.7Ca0.2Ba0.1MnO3 (LCBMO) manganites have been studied systematically. It is found that the sintering temperature could affect the micro-structures and the magnetic properties of these compounds intensively. The variations in the magnetic properties as a function of the particle size may be attributed to the local lattice distortion. With increase in the particle size, the Griffiths-phase-like behavior of susceptibility around the paramagnetic region is gradually suppressed. Furthermore, the maximum magnetic entropy change -Delta S-M(max) gradually increases with increase in the particle size. For the sample with the largest particle size (7600 nm), the values of -Delta S-M(max) were approximately 5.95 and 3.82 J/kg K with the magnetic field changes Delta H=45 and 20 kOe, respectively. The relative cooling power (RCP) exhibits the non-monotonic dependence on the particle size. The maximum values of RCP could reach 239.6 and 102.9 J/kg with Delta H=45 and 20 kOe, respectively, indicating LCBMO manganites could be promising candidates for the refrigerant materials of magnetic refrigerators. (c) 2010 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.5
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

Observation and Manipulation of a Phase Separated State in a Charge Density Wave Material

Sean M. Walker, Tarun Patel, Junichi Okamoto, Deler Langenberg, E. Annelise Bergeron, Jingjing Gao, Xuan Luo, Wenjian Lu, Yuping Sun, Adam W. Tsen, Jonathan Baugh

Summary: This study investigates the properties of ultrathin 1T-TaS2 and reveals the presence of nonequilibrium phases consisting of intertwined NC-like and C-like domains. The relationship between electronic inhomogeneity and bulk resistivity in ultrathin 1T-TaS2 is also explored.

NANO LETTERS (2022)

Article Chemistry, Physical

Modulation of electronic state in copper-intercalated 1T-TaS2

Wenhao Zhang, Degong Ding, Jingjing Gao, Kunliang Bu, Zongxiu Wu, Li Wang, Fangsen Li, Wei Wang, Xuan Luo, Wenjian Lu, Chuanhong Jin, Yuping Sun, Yi Yin

Summary: Intercalation is an effective method to modify physical properties and induce novel electronic states of transition metal dichalcogenide materials. In this study, the successful synthesis of copper-intercalated 1T-TaS2 is reported, and the structural and electronic modifications are characterized using various techniques. The intercalated copper atom suppresses the commensurate charge density wave phase and two specific electronic modulations are discovered in the near-commensurate charge density wave phase.

NANO RESEARCH (2022)

Article Chemistry, Multidisciplinary

Colossal 3D Electrical Anisotropy of MoAlB Single Crystal

Yanan Huang, Jianguo Si, Shuai Lin, Hongyan Lv, Wenhai Song, Ranran Zhang, Xuan Luo, Wenjian Lu, Xuebin Zhu, Yuping Sun

Summary: This study reports the colossal 3D electrical anisotropy of layered MAB-phase MoAlB single crystal. Through experimental and theoretical investigations, it is demonstrated that the crystal structure, chemical bond, phonon vibration, and electronic structure of MoAlB result in its significant electrical conductivity anisotropy. This work provides valuable insights for the design of functional electronic devices and the synthesis of new 2D materials.

SMALL (2022)

Article Materials Science, Multidisciplinary

Visualizing the evolution from Mott insulator to Anderson insulator in Ti-doped 1T-TaS2

Wenhao Zhang, Jingjing Gao, Li Cheng, Kunliang Bu, Zongxiu Wu, Ying Fei, Yuan Zheng, Li Wang, Fangsen Li, Xuan Luo, Zheng Liu, Yuping Sun, Yi Yin

Summary: The electronic evolution of Ti-doped 1T-TaS2 is studied using scanning tunneling microscopy (STM), revealing the emergence of a clover-shaped orbital texture and a transition from insulator to metal. Trapped electrons are directly visualized in dI/dV conductance maps, providing insights into the electronic state evolution in doped strong-correlated systems.

NPJ QUANTUM MATERIALS (2022)

Article Physics, Applied

Photoinduced interlayer dynamics in Td-MoTe2: A broadband pump-probe study

Meixin Cheng, Shazhou Zhong, Nicolas Rivas, Tina Dekker, Ariel Alcides Petruk, Patrick Gicala, Kostyantyn Pichugin, Fangchu Chen, Xuan Luo, Yuping Sun, Adam W. Tsen, German Sciaini

Summary: In this study, time-resolved broadband transient reflectivity (tr-bb-TR) measurements were used to investigate the photoinduced electronic changes and dynamics of interlayer shear phonon in T-d-MoTe2 single crystal under different incident pump fluences. The results show a gradual evolution of both the photoinduced electronic changes and interlayer shear phonon Fourier spectra as a function of pump fluence, ruling out the threshold-like change associated with the ultrafast photoinduced phase transition. Additionally, a large redshift of the interlayer shear phonon Fourier spectral features suggests significant renormalization effects on the dielectrically susceptible interband transitions.

APPLIED PHYSICS LETTERS (2022)

Article Chemistry, Multidisciplinary

High-Performance Mid-IR to Deep-UV van der Waals Photodetectors Capable of Local Spectroscopy at Room Temperature

Daozhi Shen, HeeBong Yang, Christian Spudat, Tarun Patel, Shazhou Zhong, Fangchu Chen, Jian Yan, Xuan Luo, Meixin Cheng, German Sciaini, Yuping Sun, Daniel A. Rhodes, Thomas Timusk, Y. Norman Zhou, Na Young Kim, Adam W. Tsen

Summary: In this study, we demonstrate a broadband photodetector based on a two-dimensional van der Waals heterostructure, which is sensitive to light from the mid-infrared to deep-ultraviolet range at room temperature. The device exhibits high detectivity and high bandwidth, and can be miniaturized to submicron dimensions for easy measurement of local optical properties on atomic-layer-thickness samples.

NANO LETTERS (2022)

Article Multidisciplinary Sciences

Inducing and tuning Kondo screening in a narrow-electronic-band system

Shiwei Shen, Chenhaoping Wen, Pengfei Kong, Jingjing Gao, Jianguo Si, Xuan Luo, Wenjian Lu, Yuping Sun, Gang Chen, Shichao Yan

Summary: Researchers demonstrate a transition from an insulating gap to a tunable Kondo resonance in 1T-TaS2 by Pb intercalation, providing a pathway for creating and tuning many-body electronic states in layered narrow-electronic-band materials.

NATURE COMMUNICATIONS (2022)

Article Chemistry, Multidisciplinary

Origin of the Anomalous Electrical Transport Behavior in Fe-Intercalated Weyl Semimetal Td-MoTe2

Tianyang Wang, Xuan Luo, Jingjing Gao, Zhongzhu Jiang, Wei Wang, Xingcai Yang, Nan Zhou, Xiaoguang Zhu, Lei Zhang, Wenjian Lu, Wenhai Song, Hongyan Lv, Yuping Sun

Summary: Fe-intercalated T-d-FexMoTe2 single crystals (0 < x < 0.15) were successfully grown and it was found that the phase transition temperature T-S is gradually suppressed with increasing x. Theoretical calculation suggests that the increased energy of the T-d phase, enhanced transition barrier, and more occupied bands in 1T' phase is responsible for the suppression in T-S. In addition, a rho(alpha)-lnT behavior induced by Kondo effect is observed with x >= 0.08, due to the coupling between conduction carriers and the local magnetic moments of intercalated Fe atoms. A spin-glass transition occurs at approximate to 10 K for T-d-Fe0.15MoTe2. The calculated band structure of T-d-Fe0.25MoTe2 shows that two flat bands exist near the Fermi level, which are mainly contributed by the d(yz) and dx2-y2 orbitals of the Fe atoms. The electronic phase diagram of T-d-FexMoTe2 is established for the first time in this work.

ADVANCED MATERIALS (2023)

Article Physics, Applied

Large linear magnetoresistance and nontrivial band topology in In3Rh

Linlin An, Jianguo Si, Xiangde Zhu, Chuanying Xi, Nanyang Xu, Yuanjun Yang, Lan Wang, Wei Ning, Wenjian Lu, Mingliang Tian

Summary: We report experimental studies on the angular-dependent magnetoresistance (MR) of In3Rh single crystals under high magnetic fields. The crystals exhibit large, non-saturating linear MR and remarkable quantum oscillations with multi-frequencies. Analysis of the quantum oscillations reveals the presence of three bands hosting a nontrivial Berry phase, which is supported by first-principles calculations. Our work provides a platform for exploring topological materials in indium-rich transition metal compounds.

APPLIED PHYSICS LETTERS (2023)

Article Physics, Multidisciplinary

Neel Spin Currents in Antiferromagnets

Ding-Fu Shao, Yuan-Yuan Jiang, Jun Ding, Shu-Hui Zhang, Zi-An Wang, Rui-Chun Xiao, Gautam Gurung, W. J. Lu, Y. P. Sun, Evgeny Y. Tsymbal

Summary: It is demonstrated that fully compensated antiferromagnets can support Néel spin currents, which can be used to drive spin-dependent transport phenomena in antiferromagnetic tunnel junctions (AFMTJs). The study uncovers the potential of fully compensated antiferromagnets and opens a new route for efficient information writing and reading in antiferromagnetic spintronics.

PHYSICAL REVIEW LETTERS (2023)

Article Materials Science, Multidisciplinary

Evolution of ground state in Cr2Te3 single crystal under applied magnetic field

Z. Z. Jiang, X. Liang, X. Luo, J. J. Gao, W. Wang, T. Y. Wang, X. C. Yang, X. L. Wang, L. Zhang, Y. Sun, P. Tong, J. F. Hu, W. H. Song, W. J. Lu, Y. P. Sun

Summary: The study on two-dimensional magnetic material Cr2Te3 reveals its response to external stimuli and the transition between different magnetic phases. The material undergoes a first-order phase transition from low-temperature ferromagnetic phase to antiferromagnetic phase, and a second-order phase transition between antiferromagnetic and paramagnetic phases. The material also exhibits strong spin-lattice coupling and notable negative thermal expansion and magnetostriction characteristics.

PHYSICAL REVIEW B (2022)

Article Materials Science, Multidisciplinary

Spin-neutral tunneling anomalous Hall effect

Ding-Fu Shao, Shu-Hui Zhang, Rui-Chun Xiao, Zi-An Wang, W. J. Lu, Y. P. Sun, Evgeny Y. Tsymbal

Summary: In this study, we demonstrate the realization of a spin-neutral tunneling anomalous Hall effect (TAHE) in an antiferromagnetic (AFM) tunnel junction driven by spin-neutral currents. We show that the symmetry mismatch between the AFM electrode and the nonmagnetic barrier with strong spin-orbit coupling (SOC) results in spin-dependent momentum filtering, generating transverse Hall currents in each electrode. This finding opens up new possibilities for research in magnetoelectronics and spintronics.

PHYSICAL REVIEW B (2022)

Article Physics, Multidisciplinary

Field-induced topological Hall effect in antiferromagnetic axion insulator candidate EuIn2As2

J. Yan, Z. Z. Jiang, R. C. Xiao, W. J. Lu, W. H. Song, X. B. Zhu, X. Luo, Y. P. Sun, M. Yamashita

Summary: This study investigates the magnetotransport properties of EuIn2As2 through detailed magnetoresistance and Hall measurements, revealing anomalous Hall effect and large topological Hall effect, suggesting their origins and providing insights for realizing axion insulator states.

PHYSICAL REVIEW RESEARCH (2022)

Article Materials Science, Multidisciplinary

Charge density wave and pressure-dependent superconductivity in the kagome metal CsV3Sb5: A first-principles study

Jian-Guo Si, Wen-Jian Lu, Yu-Ping Sun, Peng-Fei Liu, Bao-Tian Wang

Summary: The origin of the charge density wave (CDW) order and the superconducting properties of CsV3Sb5 under pressure are studied using first-principles calculations. The momentum-dependent electron-phonon coupling effect is found to play an important role in the formation of CDW order, and the experimentally observed double superconducting domes can be explained by the movement of the van Hove singularity and the redistribution of the electron-phonon coupling. The main contribution to the electron-phonon coupling shifts from in-plane vibrational modes to out-of-plane modes with increasing pressure.

PHYSICAL REVIEW B (2022)

Article Physics, Condensed Matter

Electronic and optical properties of CdSe/ZnSe core/shell QDs within centered hydrogenic impurity and their tunability when subjected to an external electric field

A. Jbeli, N. Zeiri, N. Yahyaoui, P. Baser, M. Said

Summary: The electronic and optical properties of CdSe/ZnSe semiconductor core/shell quantum dots with hydrogenic donor impurity were investigated theoretically. The perturbation and variational methods were used to calculate the binding energy, photoionization cross-section, polarizability, and diamagnetic susceptibility of the excited impurity under various conditions. A significant stark shift in the binding energy was observed under the influence of an external electric field.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

A computational study of alkali (Na, K, Cs) doped methylammonium lead iodide perovskite

Rahat Batool, Tariq Mahmood, Sajid Mahmood, Abdul Aziz Bhatti

Summary: This study investigates the effects of alkali metal doping (Na, K, Cs) on MAPbI3 through compositional engineering. The results show that doping Na, K, and Cs can improve the phase stability, thermodynamic stability, and optical absorption of MAPbI3.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Influence of Hubbard U correction on the structural, electronic and optical properties of Kesterite Cu2XSnS4 (X= Zn, Fe)

N. A. N. M. Nor, M. A. H. Razali, W. H. A. W. K. Annuar, N. N. Alam, F. N. Sazman, N. H. M. Zaki, A. S. Kamisan, A. I. Kamisan, M. H. Samat, A. M. M. Ali, O. H. Hassan, B. U. Haq, M. Z. A. Yahya, M. F. M. Taib

Summary: This study investigates the potential of quaternary chalcogenides semiconductors as thin film solar cell absorbers using density functional theory (DFT) and density functional theory plus Hubbard U (DFT + U) approach. The results show that by applying Hubbard U terms, the electronic band gaps can be accurately predicted, providing valuable insights for finding cost-effective new thin film solar cell materials.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

A modified drop-casting technique for efficient lead-free, environment-friendly thin film CsBi3I10 perovskite solar cells

Ashwani Kumar, Anuj Kumar, Mohaseen S. Tamboli, Mohd Ubaidullah, J. Jayarubi, S. K. Tripathi

Summary: In this study, lead-based perovskite solar cells are replaced by bismuth-based perovskite cells to overcome their instability and toxicity. CsBi3I10 perovskite films are fabricated using a modified drop-casting process, and the effects of post-annealing temperature on the morphological, structural, and optical properties are investigated. The photovoltaic performance of the cells without a hole transport layer is also quantitatively evaluated.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Phase stability, elastic properties, and hardness of Ti1-xAlxN from first-principles calculations

Yang Gao, Shu-Ming Chen, Shuo Cao, Shang-Zhou Zhang, Philippe Djemia, Qing-Miao Hu

Summary: This study investigates the phase stability, elastic modulus, and hardness of ternary nitride Ti1-xAlxN. It is found that the hardness increases with the Al content x. The cubic B1 structure is more stable for x < about 0.75, while the hexagonal structure (B4) is more stable for x > about 0.75. The composition dependent hardness and phase decomposition contribute to the convex shaped hardness curve of Ti1-xAlxN.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Piezoelectric response enhancement of w-AlN by Hf (or Zr) and Sc co-alloying: A first principles study

Fengqi Wang, Qinyan Ye, Xulin He, Kun Luo, Xiaolong Ran, Xingping Zheng, Cheng Liao, Ru Li

Summary: This report uses rigorous calculations based on density functional theory to study the piezoelectric and elastic properties of wurtzite aluminum nitride (w-AlN) with single- and co-alloying by Hf (or Zr) and Sc. The research finds that the (HfSc)0.375Al0.625N and (ZrSc)0.375Al0.625N with stable wurtzite phase have a large piezoelectric coefficient d33 of 49.18 pC/N and 47.00 pC/N, respectively. However, the piezoelectric voltage constant g33 and electromechanical coupling constant k233 of HfAlN, ZrAlN, HfScAlN, and ZrScAlN are smaller than that of ScAlN, which is attributed to the large dielectric constant epsilon 33 of Hf (or Zr) alloying samples. Furthermore, the calculations of internal parameter u and bond angle alpha elucidate the brittle-to-ductile transformation in alloying w-AlN crystal structure. Electronic structure calculations show that the bandgap decreases almost linearly with the increase of alloying concentration, and the Hf (or Zr) alloying compounds become n-type semiconductors due to the existing high-charge states.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Ho6FeSb2: Potential magnetic refrigerant with improved magnetocaloric effect

S. R. Athul, K. Arun, S. Swathi, U. D. Remya, Andrea Dzubinska, Marian Reiffers, Nagalakshmi Ramamoorthi

Summary: The magnetic and magnetocaloric characteristics of Ho6FeSb2 have been studied. The compound exhibits two second-order ferromagnetic transitions, enabling hysteresis-free magnetocaloric effect across a wide temperature range. The alloy has high relative cooling power and magnetoresistance, making it suitable for hysteresis-free magnetocaloric applications.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Structural, dielectric and magnetic study of double perovskite La2CoMnO6

Reena Sharma, Neelam Hooda, Ashima Hooda, Satish Khasa

Summary: A polycrystalline double perovskite La2CoMnO6 sample was prepared and its structural, dielectric and magnetic properties were investigated. The sample exhibited complex structures and magnetic behavior, and showed good conductivity and dielectric performance. Its multi-domain magnetic structure suggests its suitability for memory device applications.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

DFT study of RhTiP half Heusler semiconductor: Revealing its mechanical, optoelectronic, and thermoelectric properties

Shubha Dubey, Jisha A. Abraham, Kumud Dubey, Vineet Sahu, Anchit Modi, G. Pagare, N. K. Gaur

Summary: This study investigates the optoelectronic, thermodynamic, thermoelectric, and mechanical stability properties of RhTiP Half Heusler semiconductors. The results show that RhTiP is a non-magnetic material with confirmed mechanical stability. It is found to be an indirect-bandgap semiconductor with a good Seebeck coefficient. This study suggests that RhTiP has promising applications in the thermoelectric and optoelectronic fields.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Designing vibrant and bright transmission colors with multilayer film structures

Xun Xie, Jiong-Ju Hao, Hong-Wei Yang

Summary: This work presents a multilayer film structure that uses optical resonance to prepare highly efficient and saturated red, green, and blue transmittance colors. Numerical simulations and analysis show that the structure can produce R, G, and B colors with a purity comparable to standard RGB colors, while maintaining efficient transmission efficiency and obtaining a rich variety of structural colors. Additionally, a metallic interlayer is introduced to selectively suppress resonances in the short-wavelength region, improving the purity of the red color. The study also investigates the effect of the incidence angle on color purity and transmission efficiency.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Prediction of binary mutual solubility via liquid-liquid interfacial tension

Yueqiang Zhao

Summary: Solubility property is of great interest in chemical, physical, pharmaceutical, material, and environmental sciences. Understanding the intrinsic reason behind solubility behavior is a fascinating task. The theoretical relation between binary mutual solubility and liquid-liquid interfacial tension has been derived, where the partitioning of solute molecules between two coexisting liquid phases is determined by the transfer free energy per unit segment for a chain-like solute molecule expressed in terms of solute-solvent interfacial tension. This general theory of solubility is in good agreement with experimental results for binary mutual solubility and molar transfer free energy of solute molecules.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Producing ZnO films that exhibited near-infrared (NIR) luminescence with a templated design procedure

Osama K. M. Bashiar, R. E. Kroon, H. C. Swart, R. A. Harris

Summary: ZnO thin films with near-infrared emission were successfully fabricated using pulsed laser deposition under vacuum conditions, without the need for additional gases or implantation methods. The NIR emission was hypothesized to be caused by defects in the ZnO film due to high energy particle impacts on the sample surface.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Influence of dielectric matrix stoichiometry on electrical and magnetoresistive properties of Fe-Zr-O nanocomposites

O. Stognei, A. Berezutskii, I. Anisimov, A. Deryabin

Summary: The influence of ZrOn matrix stoichiometry on the electrical and magnetoresistive properties of Fe-Zr-O nanocomposites has been studied. It was found that the magnetoresistive effect is not observed in composites with oxygen lack, while composites with oxygen excess show magnetoresistive effect and increased resistivity. Magnetoresistivity in composites with oxygen lack only appears after heat treatment. These results can be explained by the difference in the density of localized states in the oxide matrix of the composites and the ratio between two types of conductivity.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

A study about the relationships between surface structures and electrical impedance characteristics in single-walled carbon nanotube/ polyester composites

Mehmet Bayirli, Aykut Ilgaz, Orhan Zeybek

Summary: The present study aims to understand the relationship between impedance characteristics and fractal behaviors. By producing neat and carbon nanotube doped composite specimens, the researchers investigated the electrical properties and surface heteromorphology using Nyquist plots and fractal analysis.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Enhancing perovskite solar cells: Tailoring the properties of Ti-doped MAPbBr3 for reduced recombination and improved efficiency

M. I. Khan, Saddam Hussain, Muhamad Saleem, Fatimah Mohammed Alzahrani, Muhammad Siddique, M. S. Hassan, Allah Ditta Khalid, Munawar Iqbal

Summary: The sol-gel method was used to deposit Ti-doped MAPbBr3 films on FTO-glass substrates with different doping ratios (0%, 4%, and 6%). XRD analysis confirmed the cubic structure of all films, and the 4% Ti-doped film exhibited a large grain size, low band gap energy, and high refractive index. Solar cells fabricated using the 4% Ti-doped MAPbBr3 film showed improved performance in terms of current density, open circuit voltage, fill factor, and efficiency.

PHYSICA B-CONDENSED MATTER (2024)