4.5 Article

Structural analysis of amorphous silica prepared by water glass-based precursors and its thermal, spectral characterization

Journal

PHYSICA B-CONDENSED MATTER
Volume 405, Issue 5, Pages 1316-1320

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.physb.2009.11.076

Keywords

X-ray diffraction; Amorphous solids; Silica; Short-range order

Funding

  1. Ningbo Science & Technology Bureau [2006B100064, 2008A610060]
  2. Science Foundation of Zhejiang Province [Y407058]
  3. K.C.Wong Magna Fund in Ningbo University

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The chemico-physical properties, near infrared and TG-DTA behavior of the non-crystalline silica prepared by water glass with different initial concentrations were systematically investigated. The structural parameters obtained by X-ray diffraction technique showed that the short range order was no more than 5-6 atoms. The variations of calculated co-ordination number and Si-O bond length, which to some extent reflected the structural compactness, explained the variation of the measured oil absorption well. (C) 2009 Published by Elsevier B.V.

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