Review
Metallurgy & Metallurgical Engineering
Yujin Nie, Jianwei Dai, Xuan Li, Xiaobo Zhang
Summary: Corrosion is a major drawback for the wide applications of Mg alloys, with attention being drawn to the corrosion behaviors of alloys with stacking fault or long period stacking ordered structures. However, the corrosion mechanisms of these alloys remain unclear, calling for further research and improvement.
JOURNAL OF MAGNESIUM AND ALLOYS
(2021)
Article
Nanoscience & Nanotechnology
Kai Guan, Mariko Egami, Daisuke Egusa, Hajime Kimizuka, Michiaki Yamasaki, Yoshihito Kawamura, Eiji Abe
Summary: In this study, SRO solute clusters in the I-1 type LPSO phases in Mg-CoY alloys have been investigated using atomic-resolution STEM and first-principles calculations. The Co3Y5 SRO cluster model embedded across the I-1-type SFs has been successfully constructed to enhance the energetic stability of the LPSO phases. The findings reveal the crucial role of solute SRO clusters in the formation and stability of LPSO phases in ternary Mg alloys.
SCRIPTA MATERIALIA
(2022)
Article
Materials Science, Multidisciplinary
Ning Su, Qingchen Deng, Yujuan Wu, Liming Peng, Kun Yang, Qiang Chen
Summary: This paper investigates the dissolution, refinement, and re-precipitation of LPSO structure/SFs in an Mg-Gd-Zn-Mn alloy through hot extrusion. The results suggest that refinement is dominated by the misalignment and re-dissolution mechanisms, with dislocation slips and rapid solute atom diffusion playing key roles. The evolution model of LPSO structure/SFs during continuous dynamic recrystallization is proposed based on the findings.
MATERIALS CHARACTERIZATION
(2021)
Article
Materials Science, Multidisciplinary
Qianqian Jin, Xiaohong Shao, Shijian Zheng, Yangtao Zhou, Bo Zhang, Xiuliang Ma
Summary: Understanding the interface structure between strengthening precipitates and matrix in alloys at the atomic level is crucial for tailoring the mechanical properties. High-resolution scanning transmission electron microscopy was used to study the semi-coherent interfaces in Mg-Zn-Y alloys, revealing unique features such as Shockley partial dislocations and dissociated structures. The interaction between dislocation arrays and solute atoms plays a key role in the stability and morphology of these interfaces, influencing the lateral growth of LPSO phases in Mg alloys.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Chemistry, Physical
Q. Q. Jin, X. H. Shao, M. Lv, B. Zhang, C. Liu, Y. M. Li, X. L. Ma
Summary: This study examined the stacking disordered structures in Mg-Co-Y as-cast alloys, which mainly consist of F-blocks, T-blocks, 2-Mg, 3-Mg, and 4-Mg. These components can form complex structures with similar stacking characters, and their stacking sequence, periodicity, and symmetry have been characterized. The structural similarity and difference between SD structures and LPSO structures were analyzed by comparing their stacking sequences and cluster arrangements.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Nanoscience & Nanotechnology
Kaixuan Li, Yuanlin Zhuang, Ligong Zhao, Dongshan Zhao, He Zheng, Shuangfeng Jia, Ying Zhang, Peili Zhao, Jianian Gui, Jianbo Wang
Summary: The study investigated the interaction between deformation twinning and long period stacking ordered (LPSO) structures in an Mg-based alloy, showing the hindrance of LPSO structures and stacking faults to twinning. The in-situ experiments revealed that thick LPSO plates effectively retard the twinning propagation, and the closer spacing between LPSO structures further suppresses twin propagation. Additionally, the study discussed the resistance of stacking faults to twinning at the atomic scale, and the strengthening effect of LPSO structures on suppressing twinning growth.
SCRIPTA MATERIALIA
(2022)
Article
Materials Science, Multidisciplinary
Tsubasa Tokuzumi, Masatoshi Mitsuhara, Shigeto Yamasaki, Tomonari Inamura, Toshiyuki Fujii, Hideharu Nakashima
Summary: The excellent mechanical properties of Mg-Zn-Y alloys with a Mg-based long-period stacking ordered (LPSO) phase are attributed to the kink bands formed by plastic deformation. This study investigated the strengthening mechanism of kink bands in directionally solidified single-phase LPSO Mg85Zn6Y9 alloys. It was found that the presence of disclinations and dislocation pile-ups contribute to the kink-band strengthening. The study provides insights into the factors responsible for kink-band strengthening in LPSO-phase Mg alloys.
Article
Materials Science, Multidisciplinary
Jing Tian, Ge Yang, Zehua Lei, Jiehua Huang, Zhiwen Zhang, Jianhui Xie
Summary: The microstructure, biocorrosion resistance, and osteogenesis performances of as-cast Mg-Zn-Y-Mn alloys with different volume fraction of long period stacking ordered (LPSO) structure were investigated. 18R-LPSO phase can be formed in the alloys, and its volume fraction increases with the elevating Zn and Y content. The corrosion mechanism of the three alloys is dominated by the micro-galvanic effect between cathodic LPSO and anodic α-Mg, resulting in the accelerating corrosion rate with the increasing volume fraction of LPSO phase.
Article
Materials Science, Multidisciplinary
Jinshu Xie, Jinghuai Zhang, Zhi Zhang, Qiang Yang, Kai Guan, Yuying He, Ru Wang, Hao Zhang, Xin Qiu, Ruizhi Wu
Summary: Formation of solute-enriched stacking faults (SESFs) and their transformation into long period stacking ordered (LPSO) phase in Mg alloys have been achieved in this study. The role and advantages of SESFs and LPSO phase were confirmed by experimental observations. These findings are significant for the development of high-strength and anti-corrosion Mg alloys.
Article
Metallurgy & Metallurgical Engineering
Kai Guan, Daisuke Egusa, Eiji Abe
Summary: The microstructures of an as-cast Mg97.49Ho1.99Cu0.43Zr0.09 alloy were investigated using atomic resolution high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM). The study revealed the presence of ordered long period stacking/order (LPSO) phases and short-range order (SRO) clusters embedded in stacking fault layers. The results support the importance of L1(2)-type TM6RE8 clusters in the formation of LPSO phases.
JOURNAL OF MAGNESIUM AND ALLOYS
(2022)
Article
Materials Science, Multidisciplinary
Qiang Yang, Shuhui Lv, Zixiang Yan, Xiru Hua, Xin Qiu, Jian Meng
Summary: This study reveals strong ductility asymmetry in extruded Mg alloys containing LPSO plates, which is mainly caused by deformation steps in LPSO plates, contributing significantly to compressive ductility. The results provide fundamental insights into deformation modes and mechanisms of thin LPSO plates, as well as a better understanding of the ductility asymmetry in extruded Mg alloys containing LPSO plates.
MATERIALS & DESIGN
(2021)
Review
Materials Science, Multidisciplinary
Mohammad Saleh Geshani, Parastoo Mahmoud Kalayeh, Amir Hossein Asadi, Hamed Mirzadeh, Mehdi Malekan, Massoud Emamy
Summary: Due to their excellent mechanical properties, magnesium alloys with long-period stacking ordered (LPSO) structures have gained significant attention. This overview article reviews the atomic structures, formation mechanisms, transformations, and morphology of LPSO phases in various Mg-based systems, as well as the effects of thermomechanical processing and severe plastic deformation techniques on the grain refinement and dispersion of LPSO phases. Furthermore, the application of friction stir processing and friction stir welding for LPSO-containing Mg alloys in terms of microstructural evolution, mechanical properties, and strengthening mechanisms is critically discussed. Future suggestions include studying the kinetics of LPSO phase formation, exploring emerging processing technologies, evaluating processing parameters, characterizing recrystallization mechanisms, and investigating superplasticity during hot deformation of LPSO-containing Mg alloys.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Materials Science, Multidisciplinary
Xiaodong Yang, Baolong Liu, Xiaojie Zhou, Weiying Huang, Liwei Lu, Xianzheng Lu, Yaru Liu
Summary: This study compares the performance of Mg-5Gd-3Y-2Zn-0.5Zr alloy with Mg-5Gd-3Y-1Zn-0.5Zr alloy. It is found that increasing the Zn content can induce the formation of more LPSO phases but has a negative impact on workability.
JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
(2023)
Article
Nanoscience & Nanotechnology
Cheng Liu, Xiaohua Yang, Jianchao Peng, Bin Liu, Qun Luo, Qian Li, Kuo-Chih Chou
Summary: The deformation behaviors of a dual-phase Mg alloy containing α-Mg and 18R-LPSO phases were investigated in this study. The 18R phase, accounting for 11.3 vol.%, contributed to 23.0% of the overall alloy deformation. The coordinated twinning deformation of α-Mg matrix through the slip of basal dislocations and the kinking deformation of Mg slices induced by the 18R phase were observed during the early stage of deformation. At the end of deformation, a large number of T2-type stacking faults were generated, improving the ductility of the alloy. This work provides a novel strategy for designing high-strength and good ductility dual-phase Mg alloys.
SCRIPTA MATERIALIA
(2023)
Article
Materials Science, Multidisciplinary
Yan Tian, Weixin Lou, Jingxin Ren, Jing Wang, Qiyuan Huang, Guangming Xie, Hongbo Xie, Jun Tan, Na Xiao, Benzhe Sun
Summary: This study investigated the structure of the basal plate in Mg-Nd-In alloy, revealing its ternary composition and close-packed structure, as well as a hexagonal stacking structure. It also discussed the thickness, aspect ratio, and orientation relationship of the basal plate with the α-Mg matrix.
MATERIALS CHARACTERIZATION
(2021)
Article
Materials Science, Multidisciplinary
Kyosuke Kishida, Yasuharu Shinkai, Haruyuki Inui
Article
Nanoscience & Nanotechnology
Nobuhiro Tsuji, Shigenobu Ogata, Haruyuki Inui, Isao Tanaka, Kyosuke Kishida, Si Gao, Wenqi Mao, Yu Bai, Ruixiao Zheng, Jun-Ping Du
SCRIPTA MATERIALIA
(2020)
Article
Materials Science, Multidisciplinary
Kyosuke Kishida, Jim Geum Kim, Tadashige Nagae, Haruyuki Inui
Article
Materials Science, Multidisciplinary
Marino Kawamura, Makoto Asakura, Norihiko L. Okamoto, Kyosuke Kishida, Haruyuki Inui, Easo P. George
Summary: The plastic deformation behavior of single crystals of the Cr-Mn-Fe-Co-Ni high-entropy alloy has been studied at different temperatures, showing sensitivity to strain rate, temperature, and crystal orientation. Solid-solution hardening is identified as the main strengthening mechanism, with deformation twinning occurring at low temperatures, impacting the material's tensile properties.
Article
Materials Science, Multidisciplinary
Kyosuke Kishida, Satoshi Nakatsuka, Hiroaki Nose, Haruyuki Inui
Summary: This study investigated the room-temperature deformation behavior of single crystals of transition-metal disilicides through micropillar compression, revealing that plastic flow is observed by the operation of the equivalent slip at room temperature for all these TM disilicides. The critical resolved shear stress (CRSS) value exhibits the 'smaller is stronger' behavior and transmission electron microscopy shows that the equivalent slip at room temperature occurs by a conventional shear mechanism for all TM disilicides.
Article
Materials Science, Multidisciplinary
Haruyuki Inui, Kyosuke Kishida, Zhenghao Chen
Summary: This paper reviews the current trend and recent progress in research on phase stability, atomic structures, mechanical and functional properties of high-entropy alloys. Since 2004, research on high-entropy alloys has spread worldwide and significant progress has been made.
MATERIALS TRANSACTIONS
(2022)
Article
Materials Science, Multidisciplinary
Kyosuke Kishida, Masaomi Okutani, Haruyuki Inui
Summary: Direct observation using Z-contrast atomic-resolution microscopy confirms the existence of zonal dislocation in the sigma phase FeCr. Understanding the dislocation core structure will improve the understanding of deformation mechanisms in complex crystal structures and provide methods to enhance the brittleness of these materials.
Article
Engineering, Mechanical
Kyosuke Kishida, Zhenghao Chen, Hirotaka Matsunoshita, Takuto Maruyama, Takayoshi Fukuyama, Yuta Sasai, Haruyuki Inui, Martin Heilmaier
Summary: The plastic deformation behavior of Mo5Si3 crystals was investigated under different conditions, revealing the influence of temperature and crystal orientation on the plastic behavior. It was found that the brittleness at room temperature is mainly due to the difficulty in dislocation motion.
INTERNATIONAL JOURNAL OF PLASTICITY
(2022)
Article
Materials Science, Multidisciplinary
Zhenghao Chen, Kyosuke Kishida, Haruyuki Inui, Martin Heilmaier, Uwe Glatzel, Gunther Eggeler
Summary: The effects of Ni and Ta additions on the mechanical properties of Co-based superalloys were investigated. The additions of Ni and Ta increased the yield strength at intermediate and high temperatures by increasing the stability of the L1(2) phase. The strength increase at intermediate temperatures can be attributed to the increased complex stacking fault energy and the increased anti-phase boundary energy on (111) planes. The strength increase at high temperatures is mainly due to the increased L1(2) solvus temperatures.
Article
Materials Science, Multidisciplinary
Le Li, Zhenghao Chen, Shogo Kuroiwa, Mitsuhiro Ito, Koretaka Yuge, Kyosuke Kishida, Hisanori Tanimoto, Yue Yu, Haruyuki Inui, Easo P. George
Summary: Short-range ordering (SRO) in the equiatomic Cr-Co-Ni medium-entropy alloy (MEA) was studied using electrical resistivity measurements and mechanical tests. SRO was found to increase gradually with time during isothermal annealing and higher temperatures led to shorter saturation time but higher saturation resistivity. Plastic deformation behavior and stress-strain curves were not significantly affected by SRO, indicating SRO has little influence on mechanical properties.
Article
Materials Science, Multidisciplinary
Kyosuke Kishida, Masaomi Okutani, Hirotaka Suzuki, Haruyuki Inui, Martin Heilmaier, Dierk Raabe
Summary: The deformation behavior of single crystals of the sigma-phase compound FeCr has been studied. Plastic flow is observed at room temperature for all loading axis orientations tested. Newly identified slip systems, in addition to the previously identified {110}[001] slip, are found to be operative at room temperature.
Article
Materials Science, Multidisciplinary
Kyosuke Kishida, Mutsumi Morisaki, Mitsuhiro Ito, Zhi Wang, Haruyuki Inui
Summary: The room temperature deformation behavior of single crystals of WC has been investigated by micropillar compression tests. The results show that plastic flow is observed when the specimen size is reduced to micrometer orders and the crystal orientation is not close to the c-axis orientation. The preference of <2 (11) over bar3> slip system on {01 (1) over bar0} prism plane is explained by considering factors such as dislocation self-energy and Peierls stress.
Article
Engineering, Mechanical
Le Li, Zhenghao Chen, Koretaka Yuge, Kyosuke Kishida, Haruyuki Inui, Martin Heilmaier, Easo P. George
Summary: The plastic deformation behavior of equiatomic Cr-Fe-Co-Ni medium-entropy alloy was investigated through compression and tension experiments. The critical resolved shear stress (CRSS) for {111}<1((1)over bar)0> slip was found to be 44-45 MPa at room temperature without significant tension-compression asymmetry. The CRSS increased rapidly with decreasing temperature, but the temperature dependence dulled below 77 K due to the inertia effect. The 0 K CRSS was determined to be 200 MPa, higher than Cr-Mn-Fe-Co-Ni high-entropy alloy but lower than Cr-Co-Ni medium-entropy alloy.
INTERNATIONAL JOURNAL OF PLASTICITY
(2023)
Article
Chemistry, Physical
Zhi Wang, Le Li, Zhenghao Chen, Koretaka Yuge, Kyosuke Kishida, Haruyuki Inui, Martin Heilmaier
Summary: A new route is proposed to achieve high strength and high ductility in Cr-Co-Ni medium entropy alloys (MEAs) by controlling the solid solution hardening parameter (MSAD) and twinning propensity parameter (SFE). Experimental results show that MSAD increases with Cr content and Ni/Co ratio, while SFE decreases with Cr content and Co/Ni ratio. Using the established connection between theoretical calculation and experimental measurement, outstanding combinations of strength and ductility are predicted and confirmed in high Cr compositions and a slightly Ni-rich side of the Co/Ni equi-composition line.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Materials Science, Multidisciplinary
Kyosuke Kishida, Mitsuhiro Ito, Haruyuki Inui, Martin Heilmaier, Gunther Eggeler
Summary: The deformation behavior of single crystals of Cr(23)C(6) was investigated by micropillar compression. The {111}<101> slip system was identified as the only operative slip system, and the dissociation of dislocations was confirmed by TEM and STEM. The stacking fault energy and the critical resolved shear stress were evaluated, and the position of the slip plane and possible dislocation dissociations were discussed. The inter-block layer slip mechanism for {111}<101> slip was deduced based on observations and calculations.
Article
Materials Science, Multidisciplinary
Nizar Lefi, Salem Neily, Roland Bonnet
Summary: This paper investigates the elastic field in a bi-material crystal with an angular dislocation line with one branch placed in the crystal and the other along a strongly bound or welded interface. The analysis formulates the elastic field of a closed dislocation loop and solves it using the knowledge of the Green's tensor of the bi-material. The study provides a faster calculation method and has important implications for solving interfacial angular dislocation problems.
PHILOSOPHICAL MAGAZINE
(2024)