4.4 Article

Microstructural characterisation of a commercial Al-Cu-Mg alloy combining transmission electron microscopy and positron annihilation spectroscopy

Journal

PHILOSOPHICAL MAGAZINE
Volume 89, Issue 13, Pages 1095-1110

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/14786430902889674

Keywords

age-hardenable alloys; precipitation; transmission electron microscopy; positron annihilation spectroscopy

Funding

  1. Agencia Nacional de Promocion Cientifica y Tecnologica [PICT 2006-1650, PID 2003-0435]
  2. Comision de Investigaciones Cientificas de la Provincia de Buenos Aires and Secretaria de Arte
  3. Ciencia y Tecnologia (UNCentro), Argentina
  4. Agencia Nacional de Promocion Cientifica y Tecnologica, Argentina [PICT 2003-RED 301]

Ask authors/readers for more resources

Transmission electron microscopy and positron annihilation spectroscopy techniques were used to characterise the microstructure of the 2024 Al-Cu-Mg commercial alloy artificially aged with and without pre-deformation. In non-deformed samples, a very dense dispersion of small, needle-shaped particles, with mean size in the order of the nanometres, was observed homogeneously distributed in the matrix, together with a coarse distribution of S-phase precipitates. In pre-deformed samples, the needle-shape particles were not seen, only a high density of S-phase precipitates nucleated on dislocations. The needle-shaped particles were identified as solute-rich Guinier-Preston-Bagaryatski (GPB) zones by combining coincidence Doppler broadening positron annihilation measurements with TEM imaging. The relationship between the microstructure and measurements of hardness and positron lifetime evolution during artificial ageing is also discussed.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.4
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Physics, Multidisciplinary

Hybrid Imaging and Timing Ps Laser Excitation Diagnostics for Pulsed Antihydrogen Production

R. Caravita, M. Antonello, A. S. Belov, G. Bonomi, R. S. Brusa, M. Caccia, A. Camper, F. Castelli, D. Comparat, G. Consolati, A. Demetrio, L. Di Noto, M. Doser, M. Fani, R. Ferragut, S. Gerber, M. Giammarchi, A. Gligorova, L. T. Gloeggler, F. Guatieri, S. Haider, A. Hinterberger, O. Khalidova, D. Krasnicky, V Lagomarsino, C. Malbrunot, S. Mariazzi, V Matveev, S. R. Mueller, G. Nebbia, P. Nedelec, M. Oberthaler, E. Oswald, D. Pagano, L. Penasa, V Petracek, F. Prelz, B. Rienaecker, O. M. Rohne, A. Rotondi, H. Sandaker, R. Santoro, G. Testera, I Tietje, V Toso, T. Wolz, C. Zimmer, N. Zurlo

ACTA PHYSICA POLONICA A (2020)

Article Instruments & Instrumentation

Sensitivity of emulsion detectors to low energy positrons

L. Anzi, A. Ariga, A. Ereditato, R. Ferragut, M. Giammarchi, G. Maero, C. Pistillo, M. Rome, E. P. Scampoli, V Toso

JOURNAL OF INSTRUMENTATION (2020)

Article Instruments & Instrumentation

A cryogenic tracking detector for antihydrogen detection in the AEgIS experiment

C. Amsler, M. Antonello, A. Belov, G. Bonomi, R. S. Brusa, M. Caccia, A. Camper, R. Caravita, F. Castelli, D. Comparat, G. Consolati, A. Demetrio, L. Di Noto, M. Doser, P. A. Ekman, M. Fani, R. Ferragut, S. Gerber, M. Giammarchi, A. Gligorova, F. Guatieri, P. Hackstock, D. Haider, S. Haider, A. Hinterberger, A. Kellerbauer, O. Khalidova, D. Krasnicky, V Lagomarsino, C. Malbrunot, S. Mariazzi, V Matveev, S. R. Mueller, G. Nebbia, P. Nedelec, L. Nowak, M. Oberthaler, E. Oswald, D. Pagano, L. Penasa, V Petracek, F. Prelz, M. Prevedelli, B. Rienaecker, J. Robert, O. M. Rohne, A. Rotondi, H. Sandaker, R. Santoro, J. Storey, G. Testera, I. C. Tietje, V Toso, T. Wolz, J. Wuethrich, P. Yzombard, C. Zimmer, N. Zurlo

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT (2020)

Article Materials Science, Ceramics

Influence of the BaTiO3 addition to K0.5Na0.5NbO3 lead-free ceramics on the vacancy-like defect structure and dielectric properties

A. Prado Espinosa, L. Ramajo, F. Rubio-Marcos, C. Macchi, A. Somoza, M. Castro

Summary: The study investigates the induced changes in the vacancy-like defect structure and dielectric properties of K0.5Na0.5NbO3 ceramics by adding various amounts of BaTiO3. Structural evolution was monitored using X-ray diffraction and Raman spectroscopy, with positron annihilation lifetime spectroscopy used to identify defect structures at a sub-nanometric scale. The discussion also highlights lattice symmetry changes and defects formed due to ion replacements in the KNN-based ceramics.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2021)

Article Instruments & Instrumentation

Real-time monitoring of a positron beam using a microchannel plate in single-particle mode

G. Vinelli, R. Ferragut, M. Giammarchi, G. Maero, M. Rome, V Toso

JOURNAL OF INSTRUMENTATION (2020)

Article Physics, Multidisciplinary

Pulsed production of antihydrogen

Claude Amsler, Massimiliano Antonello, Alexander Belov, Germano Bonomi, Roberto Sennen Brusa, Massimo Caccia, Antoine Camper, Ruggero Caravita, Fabrizio Castelli, Patrick Cheinet, Daniel Comparat, Giovanni Consolati, Andrea Demetrio, Lea Di Noto, Michael Doser, Mattia Fani, Rafael Ferragut, Julian Fesel, Sebastian Gerber, Marco Giammarchi, Angela Gligorova, Lisa Theresa Gloggler, Francesco Guatieri, Stefan Haider, Alexander Hinterberger, Alban Kellerbauer, Olga Khalidova, Daniel Krasnicky, Vittorio Lagomarsino, Chloe Malbrunot, Sebastiano Mariazzi, Viktor Matveev, Simon Muller, Giancarlo Nebbia, Patrick Nedelec, Lilian Nowak, Markus Oberthaler, Emmanuel Oswald, Davide Pagano, Luca Penasa, Vojtech Petracek, Luca Povolo, Francesco Prelz, Marco Prevedelli, Benjamin Rienacker, Ole Rohne, Alberto Rotondi, Heidi Sandaker, Romualdo Santoro, Gemma Testera, Ingmari Tietje, Valerio Toso, Tim Wolz, Pauline Yzombard, Christian Zimmer, Nicola Zurlo

Summary: Pulsed production of antihydrogen allows for control of temperature, tuning of Rydberg states, de-excitation by pulsed lasers, and manipulation through electric field gradients, marking a significant milestone for the AEgIS experiment.

COMMUNICATIONS PHYSICS (2021)

Article Multidisciplinary Sciences

An Interferometric Method for Particle Mass Measurements

Eleonora Pasino, Simone Cialdi, Giovanni Costantini, Rafael Ferragut, Marco Giammarchi, Stefano Migliorati, Massimiliano Rome, Timothy Savas, Valerio Toso

Summary: An interferometric method is proposed for measuring particle masses and their mass ratio, specifically focusing on electron and positron to detect potential symmetry violations between matter and antimatter.

SYMMETRY-BASEL (2021)

Article Physics, Condensed Matter

Positron Annihilation Spectroscopy as a Diagnostic Tool for the Study of LiCoO2 Cathode of Lithium-Ion Batteries

Gioele Pagot, Valerio Toso, Bernardo Barbiellini, Rafael Ferragut, Vito Di Noto

Summary: Positron annihilation spectroscopy using lifetime and Doppler broadening is used to characterize the lithiation state in LiCoO2 thin film in the cathode of lithium-ion batteries. The results show that the presence of graphite in between the oxide grains in real cathode Li-ion batteries causes positron spillover, which affects the measured positron parameters sensitive to delocalized electrons from lithium atoms. The first component of positron lifetime corresponds to a bulk-like state, while the second component represents a surface state at the grain-graphite interface.

CONDENSED MATTER (2021)

Review Physics, Condensed Matter

Identifying Redox Orbitals and Defects in Lithium-Ion Cathodes with Compton Scattering and Positron Annihilation Spectroscopies: A Review

Johannes Nokelainen, Bernardo Barbiellini, Jan Kuriplach, Stephan Eijt, Rafael Ferragut, Xin Li, Veenavee Kothalawala, Kosuke Suzuki, Hiroshi Sakurai, Hasnain Hafiz, Katariina Pussi, Fatemeh Keshavarz, Arun Bansil

Summary: Studying the redox mechanisms in Li-ion batteries is crucial for the rational design of next-generation battery materials. This review explores spectroscopic descriptors to gain insights into the atomic-scale characteristics of redox orbitals and provides an understanding of the workings of lithium-ion batteries.

CONDENSED MATTER (2022)

Article Physics, Fluids & Plasmas

Reducing the background temperature for cyclotron cooling in a cryogenic Penning-Malmberg trap

C. Amsler, H. Breuker, S. Chesnevskaya, G. Costantini, R. Ferragut, M. Giammarchi, A. Gligorova, G. Gosta, H. Higaki, E. D. Hunter, C. Killian, V. Kletzl, V. Kraxberger, N. Kuroda, A. Lanz, M. Leali, V. Maeckel, G. Maero, C. Malbrunot, V. Mascagna, Y. Matsuda, S. Migliorati, D. J. Murtagh, Y. Nagata, A. Nanda, L. Nowak, E. Pasino, M. Rome, M. C. Simon, M. Tajima, V. Toso, S. Ulmer, L. Venturelli, A. Weiser, E. Widmann, T. Wolz, Y. Yamazaki, J. Zmeskal

Summary: This article discusses the interaction between magnetized nonneutral plasma and the microwave environment. By using fine copper meshes and cryogenic microwave absorbing material, the effective temperature of the radiation environment can be lowered, resulting in reduced plasma temperature.

PHYSICS OF PLASMAS (2022)

Article Instruments & Instrumentation

Upgrade of ASACUSA's antihydrogen detector

V. Kraxberger, C. Amsler, H. Breuker, S. Chesnevskaya, G. Costantini, R. Ferragut, M. Giammarchi, A. Gligorova, G. Gosta, H. Higaki, E. D. Hunter, C. Killian, V. Kletzl, N. Kuroda, A. Lanz, M. Leali, V. Maeckel, G. Maero, C. Malbrunot, V. Mascagna, Y. Matsuda, S. Migliorati, D. J. Murtagh, Y. Nagata, A. Nanda, L. Nowak, E. Pasino, M. Rome, M. C. Simon, M. Tajima, V. Toso, S. Ulmer, L. Venturelli, A. Weiser, E. Widmann, T. Wolz, Y. Yamazaki, J. Zmeskal

Summary: The ASACUSA experiment aims to measure the ground state hyperfine splitting of antihydrogen to test CPT invariance. The hodoscope, consisting of scintillator bars and fibres, was successfully used with waveform digitizers for time resolution. However, the slow readout speed was improved by replacing the digitizers with TDCs reading out the ToT signal.

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT (2023)

Article Multidisciplinary Sciences

Quantum view of Li-ion high mobility at carbon-coated cathode interfaces

Gioele Pagot, Vito Di Noto, Keti Vezzu, Bernardo Barbiellini, Valerio Toso, Alberto Caruso, Meiying Zheng, Xin Li, Rafael Ferragut

Summary: Lithium-ion batteries (LIBs) are a promising power source for various applications. The cathode, with low electrical conductivity and Li-ion diffusivity, is a major bottleneck in LIBs. The carbon coating layer plays a crucial role in enhancing electrical conductivity and protecting the active material. Positron annihilation and broadband electrical spectroscopies are important tools for investigating the electronic effect of the carbon phase on cathode performance and Li-ion dynamics.

ISCIENCE (2023)

Article Physics, Condensed Matter

A Positron Implantation Profile Estimation Approach for the PALS Study of Battery Materials

Xin Li, Bernardo Barbiellini, Vito Di Noto, Gioele Pagot, Meiying Zheng, Rafael Ferragut

Summary: Positron annihilation spectroscopy is a powerful tool for investigating interfaces in materials relevant for energy storage, such as Li-ion batteries. The key to interpreting the results lies in the positron implantation profile, which is a spatial function related to the characteristics of the battery materials. We provide models for the positron implantation profile in the cathode of a Li-ion battery coin cell, allowing for reliable visualization of multilayer geometries and interfaces in thin cathodes of lithium-ion batteries.

CONDENSED MATTER (2023)

Proceedings Paper Physics, Mathematical

Protocol for pulsed antihydrogen production in the AE(g)over-barIS apparatus

I. C. Tietje, C. Amsler, M. Antonello, A. Belov, G. Bonomi, R. S. Brusa, M. Caccia, A. Camper, R. Caravita, F. Castelli, P. Cheinet, D. Comparat, G. Consolati, A. Demetrio, L. Di Noto, M. Doser, M. Fani, R. Ferragut, J. Fesel, S. Gerber, M. Giammarchi, A. Gligorova, L. T. Gloggler, F. Guatieri, S. Haider, A. Hinterberger, A. Kellerbauer, O. Khalidova, D. Krasnicky, V Lagomarsino, C. Malbrunot, L. Nowak, S. Mariazzi, V Matveev, S. R. Mueller, G. Nebbia, P. Nedelec, M. Oberthaler, E. Oswald, D. Pagano, L. Penasa, V Petracek, L. Povolo, F. Prelz, M. Prevedelli, B. Rienacker, O. M. Rohne, A. Rotondi, H. Sandaker, R. Santoro, G. Testera, V Toso, T. Wolz, P. Yzombard, C. Zimmer, N. Zurlo

SYMMETRIES IN SCIENCE XVIII (2020)

Article Physics, Multidisciplinary

Developments for pulsed antihydrogen production towards direct gravitational measurement on antimatter

M. Fani, M. Antonello, A. Belov, G. Bonomi, R. S. Brusa, M. Caccia, A. Camper, R. Caravita, F. Castelli, D. Comparat, P. Cheinet, G. Consolati, A. Demetrio, L. Di Noto, M. Doser, R. Ferragut, J. Fesel, S. Gerber, M. Giammarchi, A. Gligorova, L. T. Gloeggler, F. Guatieri, S. Haider, A. Hinterberger, A. Kellerbauer, O. Khalidova, D. Krasnicky, V Lagomarsino, C. Malbrunot, L. Nowak, S. Mariazzi, V Matveev, S. R. Mueller, G. Nebbia, P. Nedelec, M. Oberthaler, E. Oswald, D. Pagano, L. Penasa, V Petracek, L. Povolo, F. Prelz, M. Prevedelli, B. Rienaecker, O. M. Rohne, A. Rotondi, H. Sandaker, R. Santoro, G. Testera, I. C. Tietje, V Toso, T. Wolz, C. Zimmer, N. Zurlo

PHYSICA SCRIPTA (2020)

Article Materials Science, Multidisciplinary

A hybrid dislocation deforming two welded anisotropic crystals

Nizar Lefi, Salem Neily, Roland Bonnet

Summary: This paper investigates the elastic field in a bi-material crystal with an angular dislocation line with one branch placed in the crystal and the other along a strongly bound or welded interface. The analysis formulates the elastic field of a closed dislocation loop and solves it using the knowledge of the Green's tensor of the bi-material. The study provides a faster calculation method and has important implications for solving interfacial angular dislocation problems.

PHILOSOPHICAL MAGAZINE (2024)