Journal
PETROLEUM CHEMISTRY
Volume 54, Issue 4, Pages 316-322Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0965544114030098
Keywords
desulfurisation; hydrogen peroxide; diesel fuel; azacrown ethers
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Funding
- Ministry of Education and Science of the Russian Federation
- Federal Target Program Scientific-Research and Academic Personnel for Innovative Russia
- Russian Foundation for Basic Research [12-03-00260]
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Hydrogen peroxide oxidative desulfurization of model diesel fuel mixtures in the presence of azacrown ethers and their complexes with niobium pentachloride at 40-80A degrees C has been studied. It has been found that the use of complexes of azacrown ethers with NbCl5 leads to a decrease in the total sulfur content in the model mixtures to 13% of the initial amount. The structure of the azacrown ether used has little effect on the extent of desulfurization of the model mixture.
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