4.3 Article

Design of dendrimer-based nanostructured catalyst systems and their catalytic activity in hydrogenation: Synthesis of ruthenium nanoparticles immobilized in dendrimer networks

Journal

PETROLEUM CHEMISTRY
Volume 50, Issue 4, Pages 290-297

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0965544110040067

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Funding

  1. Russian Foundation for Basic Research [07-03-00221-a]
  2. Russian Federation [MD793.2009.3]

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A new method has been proposed for immobilization of 3-nm ruthenium nanoparticles on special supports synthesized for this purpose, polymer networks based on poly(propylene imine) dendrimers. It has been shown that the structure of the support has a substantial effect on the size of particles and their catalytic activity in the hydrogenation reactions of unsaturated and aromatic compounds. The catalysts can be reused without loss of activity.

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