Journal
ORGANOMETALLICS
Volume 37, Issue 17, Pages 2832-2836Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.8b00457
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Funding
- Shanghai Institute of Materia Medica, Chinese Academy of Sciences
- Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences
- NSFC [21472211, 21502212, 21772211]
- Youth Innovation Promotion Association CAS [2014229, 2018293]
- Institutes for Drug Discovery and Development, Chinese Academy of Sciences [CASIMM 0120163006]
- Science and Technology Commission of Shanghai Municipality [17JC1405000]
- NSF under the CCI Center for Selective C-H Functionalization [CHE-1205646]
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The first copper-mediated diastereoselective C-H thiolation of ferrocenes has been developed. A chiral oxazoline directing group with tert-butyl substituent is essential to the high diastereoselectivity ratio and the suppression of overreaction of monothiolated products. This reaction tolerated various functional groups on arylthiols, implying its potential application in N,S-bidentate planar chiral ligands.
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