Journal
ORGANOMETALLICS
Volume 33, Issue 14, Pages 3669-3672Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om5005513
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Funding
- MEXT [21245028, 25708018, 23105546]
- Adaptable and Seamless Technology transfer program through target driven R&D (A-STEP) from the JST [AS2525804M]
- Grants-in-Aid for Scientific Research [25105736, 25708018] Funding Source: KAKEN
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A Pd(0)-catalyzed Hiyama coupling reaction of tetrafluoroethylene (TFE) proceeded without the use of a base to give alpha,beta,beta-trifluorostyrene derivatives. A Ni(0)-catalyzed Hiyama coupling reaction of perfluoroarenes also occurred without a base. The key intermediate in these reactions would be a transition-metal fluoride complex that is generated in situ by the oxidative addition of a C-F bond.
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