Journal
ORGANOMETALLICS
Volume 33, Issue 19, Pages 5093-5096Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om5008117
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- National Science Centre [Maestro DEC-2012/04/A/STS/00595]
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Reactions of diethylzinc with TEMPO were investigated. Dropwise addition of 1 equiv of TEMPO to Et2Zn at -10 degrees C leads to the nitroxide complex EtZn(TEMPO) in high yield, whereas upon addition of 2 equiv of TEMPO the corresponding homoleptic nitroxide compound Zn(TEMPO)(2) is formed. Diffusion ordered NMR spectroscopy experiments revealed that both zinc nitroxide compounds exist in monomeric forms in solution, while single-crystal X-ray diffraction confirmed their dimeric structure in the solid state.
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