Journal
ORGANOMETALLICS
Volume 32, Issue 18, Pages 5034-5037Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om400805v
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Funding
- ND EPSCoR through NSF [EPS-0814442]
- University of North Dakota
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A manganese salen complex is shown to be an effective (pre)catalyst in the hydrosilylation of aldehydes and ketones. The present system features an earth-abundant and inexpensive base metal, low catalyst loading, and functional group tolerance. Mechanistic studies suggest that the reaction likely proceeds through a reduced manganese(III) hydride species that undergoes electrophilic attack by the carbonyl substrates.
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