4.5 Article

Chemoselective Oxidation of Secondary Alcohols Using a Ruthenium Phenylindenyl Complex

Journal

ORGANOMETALLICS
Volume 32, Issue 2, Pages 660-664

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om301156v

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Funding

  1. seventh framework program [P-FP 211468-2-EUMET]
  2. Royal Society

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A straightforward catalytic alcohol oxidation procedure using the recently reported complex [RuCl(PPh3)(2)(3-phenylindenyl)] (1) with KHMDS as cocatalyst, in acetone as the oxidant, is reported. Complex 1 shows remarkable chemoselectivity in oxidizing secondary alcohols to ketones.

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