Journal
ORGANOMETALLICS
Volume 31, Issue 8, Pages 3426-3430Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om300219f
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- Funding Program for Next Generation World-Leading Researchers [GR025]
- JSPS
- Grants-in-Aid for Scientific Research [11J09799] Funding Source: KAKEN
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The enantioselective propargylic alkylation of propargylic alcohols with beta-keto phosphonates in the presence of a thiolate-bridged diruthenium complex and a copper complex as cocatalysts gives the corresponding propargylic alkylated products in excellent yields with high diastereo- and enantioselectivities (up to 97% ee).
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