Journal
ORGANOMETALLICS
Volume 30, Issue 13, Pages 3461-3463Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om200377e
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [21655022]
- Grants-in-Aid for Scientific Research [23750063, 21655022, 09F09738] Funding Source: KAKEN
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Thermal reaction of RSH with Et(3)SiH in the presence of a catalytic amount of CpFe(CO)(2)Me exhibited dehydrogenative S-Si coupling to give RSSiEt(3). A plausible reaction mechanism is proposed involving an Fe(IV) complex with SR, SiEt(3), and H ligands, from which reductive elimination of SR and SiEt3 takes place to give RSSiEt(3).
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