Journal
ORGANOMETALLICS
Volume 30, Issue 15, Pages 4074-4086Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om200375s
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Funding
- MENR
- CNRS
- UVSQ
- UPSud-11
- PRES Universud Paris
- CICYT [CTQ2010-16237]
- Generalitat de Catalunya [2009/SGR/00279]
- ENSCCF
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The synthesis of N,N-bidentate ligands based on a pi-deficient N-heterocyclic pyridylmethylamine core is described. The preparation and characterization of the corresponding N,N-ligand palladium complexes in solution and the solid state are illustrated. Pd complexes showed a good yield, and moderate catalytic activity (up to 40% cc) in the asymmetric Suzuki-Miyaura coupling reaction, leading to methoxybinaphthyl derivatives. The combination of N,N-pyridylmethylamines with cuprous iodide revealed effective catalytic systems in oxidative naphthol derivative coupling reactions, affording the corresponding binaphthyls in high yields and with enantioselectivities of up to 61%.
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