Journal
ORGANOMETALLICS
Volume 30, Issue 3, Pages 375-378Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om1009928
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Funding
- National Natural Science Foundation of China [20702001, 21072004, 20832001]
- Ministry of Education [20103424110001]
- Anhui Education Department [TD200707, KJ2007A011]
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A novel N-N coupling reaction was developed through the oxidation of rare-earth-metal-nitrogen bonds produced by treatment of the easily available rare-earth-metal amides [(Me3Si)(2)N](3)RE(mu-Cl)Li(THF)(3) with aromatic primary or secondary amines. The reaction provides the symmetrical or unsymmetrical azo compounds and hydrazine derivatives in good to high yields within a very short time under mild conditions.
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