Journal
ORGANOMETALLICS
Volume 29, Issue 12, Pages 2823-2826Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om100226d
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Funding
- The Netherlands Organisation for Scientific Research Chemical Sciences (NWO-CW) [700.55.426]
- European Research Council (ERC, EU) [202886-CatCIR]
- University of Amsterdam
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Stereoselective polymerization of carbenes from diazo esters mediated by[(L-prolinate)Rh-1(Me(2)cod)] allows the formation of highly syndiotactic, fully functionalized carbon-chain polymers with the highest reported molecular weights in high yields, thus providing the best currently available catalyst for this new reaction.
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